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Performance study of μDMFC with foamed metal cathode current collector

Micro Direct Methanol Fuel Cells (μDMFCs) often have application in moveable power due to their green and portable nature. In a μDMFC's structure, a current collector of the μDMFC needs to have high corrosion resistance such that the μDMFC can work for a long time in a redox reaction and respon...

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Autores principales: Zhang, Fan, Zhang, Yanhui, Luo, Chuan, Zhang, Dacheng, Zhao, Zhengang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981057/
https://www.ncbi.nlm.nih.gov/pubmed/35425416
http://dx.doi.org/10.1039/d2ra00246a
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author Zhang, Fan
Zhang, Yanhui
Luo, Chuan
Zhang, Dacheng
Zhao, Zhengang
author_facet Zhang, Fan
Zhang, Yanhui
Luo, Chuan
Zhang, Dacheng
Zhao, Zhengang
author_sort Zhang, Fan
collection PubMed
description Micro Direct Methanol Fuel Cells (μDMFCs) often have application in moveable power due to their green and portable nature. In a μDMFC's structure, a current collector of the μDMFC needs to have high corrosion resistance such that the μDMFC can work for a long time in a redox reaction and respond to variable environmental conditions. To this end, four cathode current collectors were prepared. The materials selected were foam stainless steel (FSS) and foam titanium (FT), with fields of hole type and grid type. The performance of μDMFC with different cathode collector types was investigated by I–V–P polarization curves, Electrochemical Impedance Spectroscopy (EIS), and discharge test. The experimental results show that the maximum power density of the hole-type FSS cathode current collector μDMFC (HFSS-μDMFC) is 49.53 mW cm(−2) at 70 °C in the methanol solution of 1 mol L(−1), which is 70.15% higher than that of the hole-type FT cathode current collector μDMFC (HFT-μDMFC). The maximum power density of the grid-type FSS cathode current collector μDMFC (GFSS-μDMFC) is 22.60 mW cm(−2), which is 11.99% higher than that of the grid-type FT cathode current collector μDMFC (GFT-μDMFC). The performance of the HFSS-μDMFC is optimal in the methanol solution of 1 mol L(−1).
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spelling pubmed-89810572022-04-13 Performance study of μDMFC with foamed metal cathode current collector Zhang, Fan Zhang, Yanhui Luo, Chuan Zhang, Dacheng Zhao, Zhengang RSC Adv Chemistry Micro Direct Methanol Fuel Cells (μDMFCs) often have application in moveable power due to their green and portable nature. In a μDMFC's structure, a current collector of the μDMFC needs to have high corrosion resistance such that the μDMFC can work for a long time in a redox reaction and respond to variable environmental conditions. To this end, four cathode current collectors were prepared. The materials selected were foam stainless steel (FSS) and foam titanium (FT), with fields of hole type and grid type. The performance of μDMFC with different cathode collector types was investigated by I–V–P polarization curves, Electrochemical Impedance Spectroscopy (EIS), and discharge test. The experimental results show that the maximum power density of the hole-type FSS cathode current collector μDMFC (HFSS-μDMFC) is 49.53 mW cm(−2) at 70 °C in the methanol solution of 1 mol L(−1), which is 70.15% higher than that of the hole-type FT cathode current collector μDMFC (HFT-μDMFC). The maximum power density of the grid-type FSS cathode current collector μDMFC (GFSS-μDMFC) is 22.60 mW cm(−2), which is 11.99% higher than that of the grid-type FT cathode current collector μDMFC (GFT-μDMFC). The performance of the HFSS-μDMFC is optimal in the methanol solution of 1 mol L(−1). The Royal Society of Chemistry 2022-02-02 /pmc/articles/PMC8981057/ /pubmed/35425416 http://dx.doi.org/10.1039/d2ra00246a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Zhang, Fan
Zhang, Yanhui
Luo, Chuan
Zhang, Dacheng
Zhao, Zhengang
Performance study of μDMFC with foamed metal cathode current collector
title Performance study of μDMFC with foamed metal cathode current collector
title_full Performance study of μDMFC with foamed metal cathode current collector
title_fullStr Performance study of μDMFC with foamed metal cathode current collector
title_full_unstemmed Performance study of μDMFC with foamed metal cathode current collector
title_short Performance study of μDMFC with foamed metal cathode current collector
title_sort performance study of μdmfc with foamed metal cathode current collector
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981057/
https://www.ncbi.nlm.nih.gov/pubmed/35425416
http://dx.doi.org/10.1039/d2ra00246a
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