Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide

An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-pho...

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Autores principales: Yu, Qiong, Yu, Kun Yi, Xu, Cai Feng, Wong, Man-Kin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981174/
https://www.ncbi.nlm.nih.gov/pubmed/35425457
http://dx.doi.org/10.1039/d1ra08753c
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author Yu, Qiong
Yu, Kun Yi
Xu, Cai Feng
Wong, Man-Kin
author_facet Yu, Qiong
Yu, Kun Yi
Xu, Cai Feng
Wong, Man-Kin
author_sort Yu, Qiong
collection PubMed
description An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-photocatalyzed isomerization of E-arylvinyl halides in a one pot sequential catalytic process.
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spelling pubmed-89811742022-04-13 Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide Yu, Qiong Yu, Kun Yi Xu, Cai Feng Wong, Man-Kin RSC Adv Chemistry An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-photocatalyzed isomerization of E-arylvinyl halides in a one pot sequential catalytic process. The Royal Society of Chemistry 2022-01-31 /pmc/articles/PMC8981174/ /pubmed/35425457 http://dx.doi.org/10.1039/d1ra08753c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Yu, Qiong
Yu, Kun Yi
Xu, Cai Feng
Wong, Man-Kin
Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide
title Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide
title_full Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide
title_fullStr Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide
title_full_unstemmed Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide
title_short Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide
title_sort visible light photocatalytic one pot synthesis of z-arylvinyl halides from e-arylvinyl acids with n-halosuccinimide
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981174/
https://www.ncbi.nlm.nih.gov/pubmed/35425457
http://dx.doi.org/10.1039/d1ra08753c
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