Photocatalytic turnover of CO(2) under visible light by [Re(CO)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))Cl] in tandem with the sacrificial donor BIH

Optimized photocatalytic conversion of CO(2) requires new potent catalysts that can absorb visible light. The photocatalytic reduction of CO(2) using rhenium(i) has been demonstrated but suffers from low turnover. Herein, we describe a [Re(CO)(3)(1-(1,10)phenanthroline-5-(4-nitro-naphthalimide))Cl]...

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Autores principales: Spear, Alyssa, Schuarca, Robson L., Bond, Jesse Q., Korter, Timothy M., Zubieta, Jon, Doyle, Robert P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981247/
https://www.ncbi.nlm.nih.gov/pubmed/35425589
http://dx.doi.org/10.1039/d1ra08261b
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author Spear, Alyssa
Schuarca, Robson L.
Bond, Jesse Q.
Korter, Timothy M.
Zubieta, Jon
Doyle, Robert P.
author_facet Spear, Alyssa
Schuarca, Robson L.
Bond, Jesse Q.
Korter, Timothy M.
Zubieta, Jon
Doyle, Robert P.
author_sort Spear, Alyssa
collection PubMed
description Optimized photocatalytic conversion of CO(2) requires new potent catalysts that can absorb visible light. The photocatalytic reduction of CO(2) using rhenium(i) has been demonstrated but suffers from low turnover. Herein, we describe a [Re(CO)(3)(1-(1,10)phenanthroline-5-(4-nitro-naphthalimide))Cl] photocatalyst, which when combined with the sacrificial donor 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole, results in selective production of formic acid and a high turnover number of 533 and turnover frequency of 356 h(−1). Single-crystal X-ray diffraction and DFT studies are also discussed.
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spelling pubmed-89812472022-04-13 Photocatalytic turnover of CO(2) under visible light by [Re(CO)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))Cl] in tandem with the sacrificial donor BIH Spear, Alyssa Schuarca, Robson L. Bond, Jesse Q. Korter, Timothy M. Zubieta, Jon Doyle, Robert P. RSC Adv Chemistry Optimized photocatalytic conversion of CO(2) requires new potent catalysts that can absorb visible light. The photocatalytic reduction of CO(2) using rhenium(i) has been demonstrated but suffers from low turnover. Herein, we describe a [Re(CO)(3)(1-(1,10)phenanthroline-5-(4-nitro-naphthalimide))Cl] photocatalyst, which when combined with the sacrificial donor 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole, results in selective production of formic acid and a high turnover number of 533 and turnover frequency of 356 h(−1). Single-crystal X-ray diffraction and DFT studies are also discussed. The Royal Society of Chemistry 2022-02-10 /pmc/articles/PMC8981247/ /pubmed/35425589 http://dx.doi.org/10.1039/d1ra08261b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Spear, Alyssa
Schuarca, Robson L.
Bond, Jesse Q.
Korter, Timothy M.
Zubieta, Jon
Doyle, Robert P.
Photocatalytic turnover of CO(2) under visible light by [Re(CO)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))Cl] in tandem with the sacrificial donor BIH
title Photocatalytic turnover of CO(2) under visible light by [Re(CO)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))Cl] in tandem with the sacrificial donor BIH
title_full Photocatalytic turnover of CO(2) under visible light by [Re(CO)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))Cl] in tandem with the sacrificial donor BIH
title_fullStr Photocatalytic turnover of CO(2) under visible light by [Re(CO)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))Cl] in tandem with the sacrificial donor BIH
title_full_unstemmed Photocatalytic turnover of CO(2) under visible light by [Re(CO)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))Cl] in tandem with the sacrificial donor BIH
title_short Photocatalytic turnover of CO(2) under visible light by [Re(CO)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))Cl] in tandem with the sacrificial donor BIH
title_sort photocatalytic turnover of co(2) under visible light by [re(co)(3)(1-(1,10) phenanthroline-5-(4-nitro-naphthalimide))cl] in tandem with the sacrificial donor bih
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981247/
https://www.ncbi.nlm.nih.gov/pubmed/35425589
http://dx.doi.org/10.1039/d1ra08261b
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