Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones

[Image: see text] The preparation of symmetrical (hetero)biaryls via arylazo sulfones has been successfully carried out upon visible light irradiation in the presence of PPh(3)AuCl as the catalyst. The present protocol led to the efficient synthesis of a wide range of target compounds in an organic-...

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Autores principales: Di Terlizzi, Lorenzo, Scaringi, Simone, Raviola, Carlotta, Pedrazzani, Riccardo, Bandini, Marco, Fagnoni, Maurizio, Protti, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981317/
https://www.ncbi.nlm.nih.gov/pubmed/35316603
http://dx.doi.org/10.1021/acs.joc.2c00225
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author Di Terlizzi, Lorenzo
Scaringi, Simone
Raviola, Carlotta
Pedrazzani, Riccardo
Bandini, Marco
Fagnoni, Maurizio
Protti, Stefano
author_facet Di Terlizzi, Lorenzo
Scaringi, Simone
Raviola, Carlotta
Pedrazzani, Riccardo
Bandini, Marco
Fagnoni, Maurizio
Protti, Stefano
author_sort Di Terlizzi, Lorenzo
collection PubMed
description [Image: see text] The preparation of symmetrical (hetero)biaryls via arylazo sulfones has been successfully carried out upon visible light irradiation in the presence of PPh(3)AuCl as the catalyst. The present protocol led to the efficient synthesis of a wide range of target compounds in an organic-aqueous solvent under photocatalyst-free conditions.
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spelling pubmed-89813172022-04-06 Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones Di Terlizzi, Lorenzo Scaringi, Simone Raviola, Carlotta Pedrazzani, Riccardo Bandini, Marco Fagnoni, Maurizio Protti, Stefano J Org Chem [Image: see text] The preparation of symmetrical (hetero)biaryls via arylazo sulfones has been successfully carried out upon visible light irradiation in the presence of PPh(3)AuCl as the catalyst. The present protocol led to the efficient synthesis of a wide range of target compounds in an organic-aqueous solvent under photocatalyst-free conditions. American Chemical Society 2022-03-22 2022-04-01 /pmc/articles/PMC8981317/ /pubmed/35316603 http://dx.doi.org/10.1021/acs.joc.2c00225 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Di Terlizzi, Lorenzo
Scaringi, Simone
Raviola, Carlotta
Pedrazzani, Riccardo
Bandini, Marco
Fagnoni, Maurizio
Protti, Stefano
Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones
title Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones
title_full Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones
title_fullStr Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones
title_full_unstemmed Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones
title_short Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones
title_sort visible light-driven, gold(i)-catalyzed preparation of symmetrical (hetero)biaryls by homocoupling of arylazo sulfones
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981317/
https://www.ncbi.nlm.nih.gov/pubmed/35316603
http://dx.doi.org/10.1021/acs.joc.2c00225
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