Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction

For the first time we describe a general method for the synthesis of previously not synthesized unsymmetrical 3,4-diarylbutadiene sulfones which can be stable convenient precursors for 2,3-diaryl-1,3-butadienes. Our method for arylation of butadiene sulfones via Heck–Matsuda reaction allows to obtai...

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Detalles Bibliográficos
Autores principales: Shurupova, Olga V., Rzhevskiy, Sergey A., Minaeva, Lidiya I., Topchiy, Maxim A., Asachenko, Andrey F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981374/
https://www.ncbi.nlm.nih.gov/pubmed/35425582
http://dx.doi.org/10.1039/d2ra00078d
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author Shurupova, Olga V.
Rzhevskiy, Sergey A.
Minaeva, Lidiya I.
Topchiy, Maxim A.
Asachenko, Andrey F.
author_facet Shurupova, Olga V.
Rzhevskiy, Sergey A.
Minaeva, Lidiya I.
Topchiy, Maxim A.
Asachenko, Andrey F.
author_sort Shurupova, Olga V.
collection PubMed
description For the first time we describe a general method for the synthesis of previously not synthesized unsymmetrical 3,4-diarylbutadiene sulfones which can be stable convenient precursors for 2,3-diaryl-1,3-butadienes. Our method for arylation of butadiene sulfones via Heck–Matsuda reaction allows to obtain unsymmetrical 3,4-diarylbutadiene sulfones with a variety of alkyl, alkoxy, nitro, ethoxycarbonyl, perfluoroalkyl and halogen substituents (30 examples) in very good yields using readily available reagents and catalysts.
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spelling pubmed-89813742022-04-13 Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction Shurupova, Olga V. Rzhevskiy, Sergey A. Minaeva, Lidiya I. Topchiy, Maxim A. Asachenko, Andrey F. RSC Adv Chemistry For the first time we describe a general method for the synthesis of previously not synthesized unsymmetrical 3,4-diarylbutadiene sulfones which can be stable convenient precursors for 2,3-diaryl-1,3-butadienes. Our method for arylation of butadiene sulfones via Heck–Matsuda reaction allows to obtain unsymmetrical 3,4-diarylbutadiene sulfones with a variety of alkyl, alkoxy, nitro, ethoxycarbonyl, perfluoroalkyl and halogen substituents (30 examples) in very good yields using readily available reagents and catalysts. The Royal Society of Chemistry 2022-02-15 /pmc/articles/PMC8981374/ /pubmed/35425582 http://dx.doi.org/10.1039/d2ra00078d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Shurupova, Olga V.
Rzhevskiy, Sergey A.
Minaeva, Lidiya I.
Topchiy, Maxim A.
Asachenko, Andrey F.
Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction
title Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction
title_full Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction
title_fullStr Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction
title_full_unstemmed Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction
title_short Highly efficient synthesis of 3,4-diarylbutadiene sulfones using Heck–Matsuda reaction
title_sort highly efficient synthesis of 3,4-diarylbutadiene sulfones using heck–matsuda reaction
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981374/
https://www.ncbi.nlm.nih.gov/pubmed/35425582
http://dx.doi.org/10.1039/d2ra00078d
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