A novel electrochemical sensor for glyphosate detection based on Ti(3)C(2)T(x)/Cu-BTC nanocomposite

The copper benzene-1,3,5-tricarboxylate (Cu-BTC) with outstanding chemical and physical properties, is a novel and promising material in the field of electrochemical sensing. However, it has significant limitations for direct application in electrochemical sensing due to the relatively weak conductivity of Cu-BTC. Here, the conductivity of Cu-BTC was improved by loading Cu-BTC onto two-dimensional Ti(3)C(2)T(x) nanosheets with high conductivity. Thanks to the synergistic effect produced by the high conductivity of Ti(3)C(2)T(x) and the unique catalytic activity of Cu-BTC, the Ti(3)C(2)T(x)/Cu-BTC nanocomposite exhibits excellent sensing performance for glyphosate, with a low limit of detection (LOD) of 2.6 × 10(−14) M and wider linear sensing range of 1.0 × 10(−13) to 1.0 × 10(−6) M. Moreover, the electrochemical sensor based on Ti(3)C(2)T(x)/Cu-BTC also shows excellent selectivity, good reproducibility and stability.