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CO(2)-Assisted asymmetric hydrogenation of prochiral allylamines

A new methodology for the asymmetric hydrogenation of allylamines takes advantage of a reversible reaction between amines and carbon dioxide (CO(2)) to suppress unwanted side reactions. The effects of various parameters (pressure, time, solvent, and base additives) on the enantioselectivity and conv...

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Detalles Bibliográficos
Autores principales: de Winter, Tamara M., Ho, Jaddie, Alridge, Christopher J., Jessop, Philip G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981594/
https://www.ncbi.nlm.nih.gov/pubmed/35424608
http://dx.doi.org/10.1039/d2ra00263a