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A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion
An imidazolium bridged macrocyclophane was synthesized as a ratiometric fluorescence sensor with aggregation-induced emission (AIE) characteristic to detect pyrophosphate anion with high selectivity among various anions. In the presence of zinc ion, macrocyclophane can form aggregates through comple...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981699/ https://www.ncbi.nlm.nih.gov/pubmed/35424634 http://dx.doi.org/10.1039/d2ra00293k |
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author | Xiong, Jia-Bin Ban, Ding-Ding Zhou, Yong-Juan Li, Jin-Zhan Chen, Si-Ru Liu, Guo-Qun Tian, Jing-Jing Mi, Li-Wei Li, Dong-Mi |
author_facet | Xiong, Jia-Bin Ban, Ding-Ding Zhou, Yong-Juan Li, Jin-Zhan Chen, Si-Ru Liu, Guo-Qun Tian, Jing-Jing Mi, Li-Wei Li, Dong-Mi |
author_sort | Xiong, Jia-Bin |
collection | PubMed |
description | An imidazolium bridged macrocyclophane was synthesized as a ratiometric fluorescence sensor with aggregation-induced emission (AIE) characteristic to detect pyrophosphate anion with high selectivity among various anions. In the presence of zinc ion, macrocyclophane can form aggregates through complexation with pyrophosphate anion and emit ratiometric fluorescence, resulting from an enhancement in its aggregate-state emission and a reduction in its monomer emission. This AIE-active macrocycle showed great potential as a ratiometric fluorescence receptor. |
format | Online Article Text |
id | pubmed-8981699 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-89816992022-04-13 A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion Xiong, Jia-Bin Ban, Ding-Ding Zhou, Yong-Juan Li, Jin-Zhan Chen, Si-Ru Liu, Guo-Qun Tian, Jing-Jing Mi, Li-Wei Li, Dong-Mi RSC Adv Chemistry An imidazolium bridged macrocyclophane was synthesized as a ratiometric fluorescence sensor with aggregation-induced emission (AIE) characteristic to detect pyrophosphate anion with high selectivity among various anions. In the presence of zinc ion, macrocyclophane can form aggregates through complexation with pyrophosphate anion and emit ratiometric fluorescence, resulting from an enhancement in its aggregate-state emission and a reduction in its monomer emission. This AIE-active macrocycle showed great potential as a ratiometric fluorescence receptor. The Royal Society of Chemistry 2022-03-01 /pmc/articles/PMC8981699/ /pubmed/35424634 http://dx.doi.org/10.1039/d2ra00293k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Xiong, Jia-Bin Ban, Ding-Ding Zhou, Yong-Juan Li, Jin-Zhan Chen, Si-Ru Liu, Guo-Qun Tian, Jing-Jing Mi, Li-Wei Li, Dong-Mi A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion |
title | A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion |
title_full | A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion |
title_fullStr | A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion |
title_full_unstemmed | A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion |
title_short | A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion |
title_sort | novel aie-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981699/ https://www.ncbi.nlm.nih.gov/pubmed/35424634 http://dx.doi.org/10.1039/d2ra00293k |
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