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A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion

An imidazolium bridged macrocyclophane was synthesized as a ratiometric fluorescence sensor with aggregation-induced emission (AIE) characteristic to detect pyrophosphate anion with high selectivity among various anions. In the presence of zinc ion, macrocyclophane can form aggregates through comple...

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Autores principales: Xiong, Jia-Bin, Ban, Ding-Ding, Zhou, Yong-Juan, Li, Jin-Zhan, Chen, Si-Ru, Liu, Guo-Qun, Tian, Jing-Jing, Mi, Li-Wei, Li, Dong-Mi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981699/
https://www.ncbi.nlm.nih.gov/pubmed/35424634
http://dx.doi.org/10.1039/d2ra00293k
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author Xiong, Jia-Bin
Ban, Ding-Ding
Zhou, Yong-Juan
Li, Jin-Zhan
Chen, Si-Ru
Liu, Guo-Qun
Tian, Jing-Jing
Mi, Li-Wei
Li, Dong-Mi
author_facet Xiong, Jia-Bin
Ban, Ding-Ding
Zhou, Yong-Juan
Li, Jin-Zhan
Chen, Si-Ru
Liu, Guo-Qun
Tian, Jing-Jing
Mi, Li-Wei
Li, Dong-Mi
author_sort Xiong, Jia-Bin
collection PubMed
description An imidazolium bridged macrocyclophane was synthesized as a ratiometric fluorescence sensor with aggregation-induced emission (AIE) characteristic to detect pyrophosphate anion with high selectivity among various anions. In the presence of zinc ion, macrocyclophane can form aggregates through complexation with pyrophosphate anion and emit ratiometric fluorescence, resulting from an enhancement in its aggregate-state emission and a reduction in its monomer emission. This AIE-active macrocycle showed great potential as a ratiometric fluorescence receptor.
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spelling pubmed-89816992022-04-13 A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion Xiong, Jia-Bin Ban, Ding-Ding Zhou, Yong-Juan Li, Jin-Zhan Chen, Si-Ru Liu, Guo-Qun Tian, Jing-Jing Mi, Li-Wei Li, Dong-Mi RSC Adv Chemistry An imidazolium bridged macrocyclophane was synthesized as a ratiometric fluorescence sensor with aggregation-induced emission (AIE) characteristic to detect pyrophosphate anion with high selectivity among various anions. In the presence of zinc ion, macrocyclophane can form aggregates through complexation with pyrophosphate anion and emit ratiometric fluorescence, resulting from an enhancement in its aggregate-state emission and a reduction in its monomer emission. This AIE-active macrocycle showed great potential as a ratiometric fluorescence receptor. The Royal Society of Chemistry 2022-03-01 /pmc/articles/PMC8981699/ /pubmed/35424634 http://dx.doi.org/10.1039/d2ra00293k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Xiong, Jia-Bin
Ban, Ding-Ding
Zhou, Yong-Juan
Li, Jin-Zhan
Chen, Si-Ru
Liu, Guo-Qun
Tian, Jing-Jing
Mi, Li-Wei
Li, Dong-Mi
A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion
title A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion
title_full A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion
title_fullStr A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion
title_full_unstemmed A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion
title_short A novel AIE-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion
title_sort novel aie-active imidazolium macrocyclic ratiometric fluorescence sensor for pyrophosphate anion
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8981699/
https://www.ncbi.nlm.nih.gov/pubmed/35424634
http://dx.doi.org/10.1039/d2ra00293k
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