Fluoranthene dyes for the detection of water content in methanol

Three novel fluoranthene dyes were obtained by cycloaddition reactions using acrylonitrile and dialkyl acetylenedicarboxylates. Their fluorescence properties in different polar–organic solvents were investigated systematically. Meanwhile, spectral changes induced by the addition of water in methanol were observed, indicating that these fluoranthenes dyes can be efficiently used to detect the water content in methanol as probes. Significantly, the practical test measurements for the water contents in methanol illustrated the measured results with the three fluorescent probes were basically consistent with the water content added artificially. This demonstrated the potential of these fluoranthene dyes as probes in measuring the water content in methanol.