Synthesis and optical spectroscopy of Na(3)Y(VO(4))(2):Eu(3+) phosphors for thermometry and display applications

A new Na(3)Y(VO(4))(2):Eu(3+) (NYVO:Eu(3+)) phosphor was prepared using the sol–gel method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to evaluate phase purity and particle size, respectively. The optical properties were investigated by UV-visible absorption, PL, and PLE spectroscopies. The absorption measurements show the formation of the vanadate host by the presence of its characteristic band in the visible region related to VO(4)(3−) groups. The experimental results show that the NYVO:Eu(3+) phosphors exhibit high-brightness and thermally stable emission. Under near-ultraviolet (UV) excitation, both the broadband emission from VO(4)(3−) groups and the sharp peak emissions from Eu(3+) ions are observed. The highest luminescence intensity was achieved for an optimal europium concentration of 15 mol%. The study of the chromaticity parameters of these compounds gives a thermally stable hot emission in the red domain, with a color purity of about 85%, which qualifies the NYVO:Eu(3+) compound as a potential phosphor for light-emitting diode (LED) applications. Thermal sensing using NYVO:Eu(3+) phosphors are based on monitoring the luminescence intensity ratio between the NYVO host emission and Eu(3+) luminescence lines. Notably, the optical thermometry of NYVO:Eu(3+) was characterized based on the fluorescence intensity ratio of VO(4)(3−) and Eu(3+) emissions in the 298–440 K range, with maximum absolute and relative sensitivities of 3.4% K(−1) and 0.0032 K(−1) respectively and a temperature uncertainty of 0.01. NYVO:Eu(3+) can then be considered as a potential red phosphor for application in ultraviolet-pumped white light-emitting diodes and as a potential optical thermometer. It provides new possibilities for the design of multifunctional materials for red light-emitting diodes and for non-contact thermometry.