The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14)

Single crystals of Tl(3)Sb(5)O(14) were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K(3)Sb(5)O(14), Rb(3)Sb(5)O(14) and Cs(3)Sb(5)O(14) analogues with ortho­rhom­bic Pbam symmet...

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Detalles Bibliográficos
Autores principales: Sicher, Paul, Stöger, Berthold
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8983969/
https://www.ncbi.nlm.nih.gov/pubmed/35492267
http://dx.doi.org/10.1107/S2056989022002869
Descripción
Sumario:Single crystals of Tl(3)Sb(5)O(14) were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K(3)Sb(5)O(14), Rb(3)Sb(5)O(14) and Cs(3)Sb(5)O(14) analogues with ortho­rhom­bic Pbam symmetry and cell parameters a = 24.2899 (9) Å, b = 7.1931 (3) Å, c = 7.4182 (3) Å. The Sb atoms form irregular [SbO(6)] octa­hedra, which are linked via edges and corners into a triperiodic network. The Tl(+) ions are located in distinct channels of the network extending along [010] and [001].

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