The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14)

Single crystals of Tl(3)Sb(5)O(14) were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K(3)Sb(5)O(14), Rb(3)Sb(5)O(14) and Cs(3)Sb(5)O(14) analogues with ortho­rhom­bic Pbam symmet...

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Detalles Bibliográficos
Autores principales: Sicher, Paul, Stöger, Berthold
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8983969/
https://www.ncbi.nlm.nih.gov/pubmed/35492267
http://dx.doi.org/10.1107/S2056989022002869
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author Sicher, Paul
Stöger, Berthold
author_facet Sicher, Paul
Stöger, Berthold
author_sort Sicher, Paul
collection PubMed
description Single crystals of Tl(3)Sb(5)O(14) were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K(3)Sb(5)O(14), Rb(3)Sb(5)O(14) and Cs(3)Sb(5)O(14) analogues with ortho­rhom­bic Pbam symmetry and cell parameters a = 24.2899 (9) Å, b = 7.1931 (3) Å, c = 7.4182 (3) Å. The Sb atoms form irregular [SbO(6)] octa­hedra, which are linked via edges and corners into a triperiodic network. The Tl(+) ions are located in distinct channels of the network extending along [010] and [001].
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spelling pubmed-89839692022-04-28 The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14) Sicher, Paul Stöger, Berthold Acta Crystallogr E Crystallogr Commun Research Communications Single crystals of Tl(3)Sb(5)O(14) were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K(3)Sb(5)O(14), Rb(3)Sb(5)O(14) and Cs(3)Sb(5)O(14) analogues with ortho­rhom­bic Pbam symmetry and cell parameters a = 24.2899 (9) Å, b = 7.1931 (3) Å, c = 7.4182 (3) Å. The Sb atoms form irregular [SbO(6)] octa­hedra, which are linked via edges and corners into a triperiodic network. The Tl(+) ions are located in distinct channels of the network extending along [010] and [001]. International Union of Crystallography 2022-03-17 /pmc/articles/PMC8983969/ /pubmed/35492267 http://dx.doi.org/10.1107/S2056989022002869 Text en © Sicher and Stöger 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sicher, Paul
Stöger, Berthold
The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14)
title The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14)
title_full The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14)
title_fullStr The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14)
title_full_unstemmed The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14)
title_short The channel structure of trithallium penta­anti­m­on­ate(V), Tl(3)Sb(5)O(14)
title_sort channel structure of trithallium penta­anti­m­on­ate(v), tl(3)sb(5)o(14)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8983969/
https://www.ncbi.nlm.nih.gov/pubmed/35492267
http://dx.doi.org/10.1107/S2056989022002869
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