Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile

In the title compound, C(14)H(14)N(2)S(3), the double-bond system of the acrylo­nitrile moiety is significantly non-planar, with absolute cis torsion angles of 13.9 (2) and 15.1 (2)°. The ring system and the double bond system subtend an inter­planar angle of 11.16 (4)°. The wide angle C—C(CN)=C of...

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Detalles Bibliográficos
Autores principales: Azzam, Rasha A., Elgemeie, Galal H., Elsayed, Rasha E., Gad, Nagwa M., Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8983987/
https://www.ncbi.nlm.nih.gov/pubmed/35492278
http://dx.doi.org/10.1107/S2056989022002572
Descripción
Sumario:In the title compound, C(14)H(14)N(2)S(3), the double-bond system of the acrylo­nitrile moiety is significantly non-planar, with absolute cis torsion angles of 13.9 (2) and 15.1 (2)°. The ring system and the double bond system subtend an inter­planar angle of 11.16 (4)°. The wide angle C—C(CN)=C of 129.40 (12)° may be associated with a balance between planarity and avoidance of a very short S⋯S contact.

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