Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile

In the title compound, C(14)H(14)N(2)S(3), the double-bond system of the acrylo­nitrile moiety is significantly non-planar, with absolute cis torsion angles of 13.9 (2) and 15.1 (2)°. The ring system and the double bond system subtend an inter­planar angle of 11.16 (4)°. The wide angle C—C(CN)=C of...

Descripción completa

Detalles Bibliográficos
Autores principales: Azzam, Rasha A., Elgemeie, Galal H., Elsayed, Rasha E., Gad, Nagwa M., Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8983987/
https://www.ncbi.nlm.nih.gov/pubmed/35492278
http://dx.doi.org/10.1107/S2056989022002572
_version_ 1784682080797458432
author Azzam, Rasha A.
Elgemeie, Galal H.
Elsayed, Rasha E.
Gad, Nagwa M.
Jones, Peter G.
author_facet Azzam, Rasha A.
Elgemeie, Galal H.
Elsayed, Rasha E.
Gad, Nagwa M.
Jones, Peter G.
author_sort Azzam, Rasha A.
collection PubMed
description In the title compound, C(14)H(14)N(2)S(3), the double-bond system of the acrylo­nitrile moiety is significantly non-planar, with absolute cis torsion angles of 13.9 (2) and 15.1 (2)°. The ring system and the double bond system subtend an inter­planar angle of 11.16 (4)°. The wide angle C—C(CN)=C of 129.40 (12)° may be associated with a balance between planarity and avoidance of a very short S⋯S contact.
format Online
Article
Text
id pubmed-8983987
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-89839872022-04-28 Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile Azzam, Rasha A. Elgemeie, Galal H. Elsayed, Rasha E. Gad, Nagwa M. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(14)H(14)N(2)S(3), the double-bond system of the acrylo­nitrile moiety is significantly non-planar, with absolute cis torsion angles of 13.9 (2) and 15.1 (2)°. The ring system and the double bond system subtend an inter­planar angle of 11.16 (4)°. The wide angle C—C(CN)=C of 129.40 (12)° may be associated with a balance between planarity and avoidance of a very short S⋯S contact. International Union of Crystallography 2022-03-10 /pmc/articles/PMC8983987/ /pubmed/35492278 http://dx.doi.org/10.1107/S2056989022002572 Text en © Azzam et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Azzam, Rasha A.
Elgemeie, Galal H.
Elsayed, Rasha E.
Gad, Nagwa M.
Jones, Peter G.
Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile
title Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile
title_full Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile
title_fullStr Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile
title_full_unstemmed Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile
title_short Crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile
title_sort crystal structure of 2-(benzo[d]thia­zol-2-yl)-3,3-bis­(ethyl­sulfan­yl)acrylo­nitrile
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8983987/
https://www.ncbi.nlm.nih.gov/pubmed/35492278
http://dx.doi.org/10.1107/S2056989022002572
work_keys_str_mv AT azzamrashaa crystalstructureof2benzodthiazol2yl33bisethylsulfanylacrylonitrile
AT elgemeiegalalh crystalstructureof2benzodthiazol2yl33bisethylsulfanylacrylonitrile
AT elsayedrashae crystalstructureof2benzodthiazol2yl33bisethylsulfanylacrylonitrile
AT gadnagwam crystalstructureof2benzodthiazol2yl33bisethylsulfanylacrylonitrile
AT jonespeterg crystalstructureof2benzodthiazol2yl33bisethylsulfanylacrylonitrile

Ejemplares similares