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Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions

Pin corrosion is a critical issue that causes premature rupture of high-voltage insulators. The development of efficient, defect-free, thermal resistive, hard, economical and environment-friendly sealing coating system is required to replace the current polymer-based highly toxic coatings for insula...

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Autores principales: Sanyal, Simpy, Kim, Taeyong, Rabelo, Matheus, Pham, Duy Phong, Yi, Junsin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8984353/
https://www.ncbi.nlm.nih.gov/pubmed/35425624
http://dx.doi.org/10.1098/rsos.211786
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author Sanyal, Simpy
Kim, Taeyong
Rabelo, Matheus
Pham, Duy Phong
Yi, Junsin
author_facet Sanyal, Simpy
Kim, Taeyong
Rabelo, Matheus
Pham, Duy Phong
Yi, Junsin
author_sort Sanyal, Simpy
collection PubMed
description Pin corrosion is a critical issue that causes premature rupture of high-voltage insulators. The development of efficient, defect-free, thermal resistive, hard, economical and environment-friendly sealing coating system is required to replace the current polymer-based highly toxic coatings for insulators. This study investigates the suitability of noble cerium (Ce)-based sealing coating film for use as an anti-corrosion coating for insulator pins installed in low-pH and highly corrosive sites. The coating bath parameters are optimized for the formation of a high-performance Ce-based protective sealing coating. After immersion in a 60 000 ppm CeCl(3).7H(2)O sealing coating bath for 60 min, a Ce-rich and dense protective coating (24 µm) is formed on the pin surface. The life expectancy of the coated pin is 2.5 times higher than that of the non-coated galvanized pins. Electrochemical experiments and microstructural analysis demonstrate that Ce-based protective layers are suitable for long-term protection of high-voltage insulator pins in low-pH and high-corrosion-rate sites. We believe that this work would pave the way of developing ecofriendly anti-corrosion coatings for electric insulators and power industries.
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spelling pubmed-89843532022-04-13 Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions Sanyal, Simpy Kim, Taeyong Rabelo, Matheus Pham, Duy Phong Yi, Junsin R Soc Open Sci Chemistry Pin corrosion is a critical issue that causes premature rupture of high-voltage insulators. The development of efficient, defect-free, thermal resistive, hard, economical and environment-friendly sealing coating system is required to replace the current polymer-based highly toxic coatings for insulators. This study investigates the suitability of noble cerium (Ce)-based sealing coating film for use as an anti-corrosion coating for insulator pins installed in low-pH and highly corrosive sites. The coating bath parameters are optimized for the formation of a high-performance Ce-based protective sealing coating. After immersion in a 60 000 ppm CeCl(3).7H(2)O sealing coating bath for 60 min, a Ce-rich and dense protective coating (24 µm) is formed on the pin surface. The life expectancy of the coated pin is 2.5 times higher than that of the non-coated galvanized pins. Electrochemical experiments and microstructural analysis demonstrate that Ce-based protective layers are suitable for long-term protection of high-voltage insulator pins in low-pH and high-corrosion-rate sites. We believe that this work would pave the way of developing ecofriendly anti-corrosion coatings for electric insulators and power industries. The Royal Society 2022-04-06 /pmc/articles/PMC8984353/ /pubmed/35425624 http://dx.doi.org/10.1098/rsos.211786 Text en © 2022 The Authors. https://creativecommons.org/licenses/by/4.0/Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, provided the original author and source are credited.
spellingShingle Chemistry
Sanyal, Simpy
Kim, Taeyong
Rabelo, Matheus
Pham, Duy Phong
Yi, Junsin
Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions
title Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions
title_full Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions
title_fullStr Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions
title_full_unstemmed Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions
title_short Application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions
title_sort application of noble cerium-based anti-corrosion sealing coating approach applied on electrical insulators installed in industrial regions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8984353/
https://www.ncbi.nlm.nih.gov/pubmed/35425624
http://dx.doi.org/10.1098/rsos.211786
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