Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines

The silver(i) and iodine(i) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(i) complex formation. The complexes were ch...

Descripción completa

Detalles Bibliográficos
Autores principales: Ward, Jas S., Gomila, Rosa M., Frontera, Antonio, Rissanen, Kari
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8984907/
https://www.ncbi.nlm.nih.gov/pubmed/35424827
http://dx.doi.org/10.1039/d2ra01390h
_version_ 1784682275793797120
author Ward, Jas S.
Gomila, Rosa M.
Frontera, Antonio
Rissanen, Kari
author_facet Ward, Jas S.
Gomila, Rosa M.
Frontera, Antonio
Rissanen, Kari
author_sort Ward, Jas S.
collection PubMed
description The silver(i) and iodine(i) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(i) complex formation. The complexes were characterised by (1)H and (1)H–(15)N HMBC NMR, X-ray crystallography, and DFT calculations. The solid-state structures for the silver(i) and iodine(i) complexes were extensively compared to the literature and analysed by DFT to examine the influence of the sterically bulky pyridines and their anions.
format Online
Article
Text
id pubmed-8984907
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-89849072022-04-13 Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines Ward, Jas S. Gomila, Rosa M. Frontera, Antonio Rissanen, Kari RSC Adv Chemistry The silver(i) and iodine(i) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate the steric limitations of iodine(i) complex formation. The complexes were characterised by (1)H and (1)H–(15)N HMBC NMR, X-ray crystallography, and DFT calculations. The solid-state structures for the silver(i) and iodine(i) complexes were extensively compared to the literature and analysed by DFT to examine the influence of the sterically bulky pyridines and their anions. The Royal Society of Chemistry 2022-03-21 /pmc/articles/PMC8984907/ /pubmed/35424827 http://dx.doi.org/10.1039/d2ra01390h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Ward, Jas S.
Gomila, Rosa M.
Frontera, Antonio
Rissanen, Kari
Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
title Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
title_full Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
title_fullStr Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
title_full_unstemmed Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
title_short Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
title_sort iodine(i) complexes incorporating sterically bulky 2-substituted pyridines
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8984907/
https://www.ncbi.nlm.nih.gov/pubmed/35424827
http://dx.doi.org/10.1039/d2ra01390h
work_keys_str_mv AT wardjass iodineicomplexesincorporatingstericallybulky2substitutedpyridines
AT gomilarosam iodineicomplexesincorporatingstericallybulky2substitutedpyridines
AT fronteraantonio iodineicomplexesincorporatingstericallybulky2substitutedpyridines
AT rissanenkari iodineicomplexesincorporatingstericallybulky2substitutedpyridines

Ejemplares similares