Mix and wait – a relaxed way for synthesizing ZIF-8

Herein we report the synthesis of a zeolitic imidazolate framework (ZIF-8) by an easy “mix and wait” procedure. In a closed vial, without any interference, the mixture of 2-methylimidazole and basic zinc carbonate assembles into the crystalline product with approx. 90% conversion after 70 h. The rea...

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Detalles Bibliográficos
Autores principales: Gugin, Nikita, Villajos, Jose A., Feldmann, Ines, Emmerling, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985132/
https://www.ncbi.nlm.nih.gov/pubmed/35424869
http://dx.doi.org/10.1039/d2ra00740a
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author Gugin, Nikita
Villajos, Jose A.
Feldmann, Ines
Emmerling, Franziska
author_facet Gugin, Nikita
Villajos, Jose A.
Feldmann, Ines
Emmerling, Franziska
author_sort Gugin, Nikita
collection PubMed
description Herein we report the synthesis of a zeolitic imidazolate framework (ZIF-8) by an easy “mix and wait” procedure. In a closed vial, without any interference, the mixture of 2-methylimidazole and basic zinc carbonate assembles into the crystalline product with approx. 90% conversion after 70 h. The reaction exhibits sigmoidal kinetics due to the self-generated water which accelerates the reaction.
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spelling pubmed-89851322022-04-13 Mix and wait – a relaxed way for synthesizing ZIF-8 Gugin, Nikita Villajos, Jose A. Feldmann, Ines Emmerling, Franziska RSC Adv Chemistry Herein we report the synthesis of a zeolitic imidazolate framework (ZIF-8) by an easy “mix and wait” procedure. In a closed vial, without any interference, the mixture of 2-methylimidazole and basic zinc carbonate assembles into the crystalline product with approx. 90% conversion after 70 h. The reaction exhibits sigmoidal kinetics due to the self-generated water which accelerates the reaction. The Royal Society of Chemistry 2022-03-22 /pmc/articles/PMC8985132/ /pubmed/35424869 http://dx.doi.org/10.1039/d2ra00740a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Gugin, Nikita
Villajos, Jose A.
Feldmann, Ines
Emmerling, Franziska
Mix and wait – a relaxed way for synthesizing ZIF-8
title Mix and wait – a relaxed way for synthesizing ZIF-8
title_full Mix and wait – a relaxed way for synthesizing ZIF-8
title_fullStr Mix and wait – a relaxed way for synthesizing ZIF-8
title_full_unstemmed Mix and wait – a relaxed way for synthesizing ZIF-8
title_short Mix and wait – a relaxed way for synthesizing ZIF-8
title_sort mix and wait – a relaxed way for synthesizing zif-8
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985132/
https://www.ncbi.nlm.nih.gov/pubmed/35424869
http://dx.doi.org/10.1039/d2ra00740a
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AT emmerlingfranziska mixandwaitarelaxedwayforsynthesizingzif8

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