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Enantioselective [1,2]-Stevens rearrangement of thiosulfonates to construct dithio-substituted quaternary carbon centers

An enantioselective [1,2] Stevens rearrangement was realized by using chiral guanidine and copper(i) complexes. Bis-sulfuration of α-diazocarbonyl compounds was developed through using thiosulfonates as the sulfenylating agent. It was undoubtedly an atom-economic process providing an efficient route...

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Detalles Bibliográficos
Autores principales: Hu, Linfeng, Li, Jinzhao, Zhang, Yongyan, Feng, Xiaoming, Liu, Xiaohua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985575/
https://www.ncbi.nlm.nih.gov/pubmed/35440994
http://dx.doi.org/10.1039/d2sc00419d