Metalation-induced denitrogenative reductive coupling of isocyanides on a silylene-bridged nickel cluster

The denitrogenative reductive coupling of two molecules of CN(t)Bu to afford a disilylketenimine with an aza-disilacyclobutane skeleton was achieved on a multinuclear silylene-bridged Ni cluster framework in the absence of any strong reducing reagents. During this reaction, sequential cleavage of a...

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Detalles Bibliográficos
Autores principales: Shimamoto, Kento, Sunada, Yusuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985577/
https://www.ncbi.nlm.nih.gov/pubmed/35440996
http://dx.doi.org/10.1039/d1sc06935g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985577/
https://www.ncbi.nlm.nih.gov/pubmed/35440996
http://dx.doi.org/10.1039/d1sc06935g

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