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Metalation-induced denitrogenative reductive coupling of isocyanides on a silylene-bridged nickel cluster
The denitrogenative reductive coupling of two molecules of CN(t)Bu to afford a disilylketenimine with an aza-disilacyclobutane skeleton was achieved on a multinuclear silylene-bridged Ni cluster framework in the absence of any strong reducing reagents. During this reaction, sequential cleavage of a...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985577/ https://www.ncbi.nlm.nih.gov/pubmed/35440996 http://dx.doi.org/10.1039/d1sc06935g |