Photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone

We present an experimental X-ray photoelectron circular dichroism (PECD) study of liquid fenchone at the C 1s edge. A novel setup to enable PECD measurements on a liquid microjet [Malerz et al., Rev. Sci. Instrum., 2022, 93, 015101] was used. For the C 1s line assigned to fenchone's carbonyl ca...

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Detalles Bibliográficos
Autores principales: Pohl, Marvin N., Malerz, Sebastian, Trinter, Florian, Lee, Chin, Kolbeck, Claudia, Wilkinson, Iain, Thürmer, Stephan, Neumark, Daniel M., Nahon, Laurent, Powis, Ivan, Meijer, Gerard, Winter, Bernd, Hergenhahn, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985659/
https://www.ncbi.nlm.nih.gov/pubmed/35253025
http://dx.doi.org/10.1039/d1cp05748k
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author Pohl, Marvin N.
Malerz, Sebastian
Trinter, Florian
Lee, Chin
Kolbeck, Claudia
Wilkinson, Iain
Thürmer, Stephan
Neumark, Daniel M.
Nahon, Laurent
Powis, Ivan
Meijer, Gerard
Winter, Bernd
Hergenhahn, Uwe
author_facet Pohl, Marvin N.
Malerz, Sebastian
Trinter, Florian
Lee, Chin
Kolbeck, Claudia
Wilkinson, Iain
Thürmer, Stephan
Neumark, Daniel M.
Nahon, Laurent
Powis, Ivan
Meijer, Gerard
Winter, Bernd
Hergenhahn, Uwe
author_sort Pohl, Marvin N.
collection PubMed
description We present an experimental X-ray photoelectron circular dichroism (PECD) study of liquid fenchone at the C 1s edge. A novel setup to enable PECD measurements on a liquid microjet [Malerz et al., Rev. Sci. Instrum., 2022, 93, 015101] was used. For the C 1s line assigned to fenchone's carbonyl carbon, a non-vanishing asymmetry is found in the intensity of photoelectron spectra acquired under a fixed angle in the backward-scattering plane. This experiment paves the way towards an innovative probe of the chirality of organic/biological molecules in aqueous solution.
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spelling pubmed-89856592022-04-18 Photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone Pohl, Marvin N. Malerz, Sebastian Trinter, Florian Lee, Chin Kolbeck, Claudia Wilkinson, Iain Thürmer, Stephan Neumark, Daniel M. Nahon, Laurent Powis, Ivan Meijer, Gerard Winter, Bernd Hergenhahn, Uwe Phys Chem Chem Phys Chemistry We present an experimental X-ray photoelectron circular dichroism (PECD) study of liquid fenchone at the C 1s edge. A novel setup to enable PECD measurements on a liquid microjet [Malerz et al., Rev. Sci. Instrum., 2022, 93, 015101] was used. For the C 1s line assigned to fenchone's carbonyl carbon, a non-vanishing asymmetry is found in the intensity of photoelectron spectra acquired under a fixed angle in the backward-scattering plane. This experiment paves the way towards an innovative probe of the chirality of organic/biological molecules in aqueous solution. The Royal Society of Chemistry 2022-02-18 /pmc/articles/PMC8985659/ /pubmed/35253025 http://dx.doi.org/10.1039/d1cp05748k Text en This journal is © the Owner Societies https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Pohl, Marvin N.
Malerz, Sebastian
Trinter, Florian
Lee, Chin
Kolbeck, Claudia
Wilkinson, Iain
Thürmer, Stephan
Neumark, Daniel M.
Nahon, Laurent
Powis, Ivan
Meijer, Gerard
Winter, Bernd
Hergenhahn, Uwe
Photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone
title Photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone
title_full Photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone
title_fullStr Photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone
title_full_unstemmed Photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone
title_short Photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone
title_sort photoelectron circular dichroism in angle-resolved photoemission from liquid fenchone
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985659/
https://www.ncbi.nlm.nih.gov/pubmed/35253025
http://dx.doi.org/10.1039/d1cp05748k
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