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An Unexpected Inactivation of N-Heterocyclic Carbene Organic Catalyst by 1-Methylcyclopropylcarbaldehyde and 2,2,2-Trifluoroacetophenone

An unprecedented inactivation process of the indanol-derived NHC catalysts bearing N-C(6)F(5) groups is reported. An unexpected multi-cyclic complex product is obtained from the 3-component reaction with the 1-methylcyclopropyl-carbaldehyde, the 2,2,2-trifluoroacetophenone and the NHC catalyst. The...

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Detalles Bibliográficos
Autores principales: Chen, Yanling, Lv, Jie, Pan, Xuling, Jin, Zhichao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8988059/
https://www.ncbi.nlm.nih.gov/pubmed/35402372
http://dx.doi.org/10.3389/fchem.2022.875286

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