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Activation of the C[double bond, length as m-dash]P bond in phosphanylphosphaalkenes (C[double bond, length as m-dash]P–P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi
Three reactions of phosphanylphosphaalkene (1) with nucleophiles were performed to activate the diphosphorus monomer. We observed similar results in the reactions with MeLi and nBuLi, in which the P–P bond is cleavaged and triphosphorus systems [P(Me)(2)–CH(biph)–CH(biph)–P–(PtBu(2))](−) (1a′′) and...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8988267/ https://www.ncbi.nlm.nih.gov/pubmed/35425069 http://dx.doi.org/10.1039/d1ra09215d |