Transition-metal-catalyzed remote C–H functionalization of thioethers

In the last decade, transition-metal-catalyzed direct C–H bond functionalization has been recognized as one of most efficient approaches for the derivatization of thioethers. Within this category, both mono- and bidentate-directing group strategies achieved the remote C(sp(2))–H and C(sp(3))–H funct...

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Detalles Bibliográficos
Autores principales: Feng, Xiao-Qing, Wang, He-Cheng, Li, Zhi, Tang, Long, Sun, Xiaoqiang, Yang, Ke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8988276/
https://www.ncbi.nlm.nih.gov/pubmed/35424975
http://dx.doi.org/10.1039/d2ra01268e
Descripción
Sumario:In the last decade, transition-metal-catalyzed direct C–H bond functionalization has been recognized as one of most efficient approaches for the derivatization of thioethers. Within this category, both mono- and bidentate-directing group strategies achieved the remote C(sp(2))–H and C(sp(3))–H functionalization of thioethers, respectively. This review systematically introduces the major advances and their mechanisms in the field of transition-metal-catalyzed remote C–H functionalization of thioethers from 2010 to 2021.

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