Cargando…

NiH-catalysed proximal-selective hydroalkylation of unactivated alkenes and the ligand effects on regioselectivity

Alkene hydrocarbonation reactions have been developed to supplement traditional electrophile-nucleophile cross-coupling reactions. The branch-selective hydroalkylation method applied to a broad range of unactivated alkenes remains challenging. Herein, we report a NiH-catalysed proximal-selective hyd...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Xiao-Xu, Xu, Yuan-Tai, Zhang, Zhi-Lin, Lu, Xi, Fu, Yao
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8990077/ https://www.ncbi.nlm.nih.gov/pubmed/35393419 http://dx.doi.org/10.1038/s41467-022-29554-4

Ejemplares similares

Radical chain repair: The hydroalkylation of polysubstituted unactivated alkenes
por: Povie, Guillaume, et al.
Publicado: (2018)

Ni-catalysed reductive arylalkylation of unactivated alkenes
por: Jin, Youxiang, et al.
Publicado: (2018)

Access to dialkylated allylic stereogenic centers by Ni-catalysed enantioselective hydrovinylation of unactivated alkenes
por: Zhang, Jian-Xin, et al.
Publicado: (2022)

Photocatalytic Hydroalkylation of Aryl-Alkenes
por: Buettner, Cornelia S., et al.
Publicado: (2022)

Divergent regioselective Heck-type reaction of unactivated alkenes and N-fluoro-sulfonamides
por: Zhao, Chunyang, et al.
Publicado: (2022)

Desymmetrization of unactivated bis-alkenes via chiral Brønsted acid-catalysed hydroamination
por: Yu, Zhang-Long, et al.
Publicado: (2020)

Ni-catalysed regioselective 1,2-diarylation of unactivated olefins by stabilizing Heck intermediates as pyridylsilyl-coordinated transient metallacycles
por: Thapa, Surendra, et al.
Publicado: (2017)

Efficient gold(I)/silver(I)-cocatalyzed cascade intermolecular N-Michael addition/intramolecular hydroalkylation of unactivated alkenes with α-ketones
por: Xiao, Ya-Ping, et al.
Publicado: (2011)

Ligand-enabled ortho-C–H olefination of phenylacetic amides with unactivated alkenes
por: Lu, Ming-Zhu, et al.
Publicado: (2017)

NiH-catalyzed anti-Markovnikov hydroamidation of unactivated alkenes with 1,4,2-dioxazol-5-ones for the direct synthesis of N-alkyl amides
por: Du, Bingnan, et al.
Publicado: (2022)

Electrochemical flow aziridination of unactivated alkenes
por: Wang, Shengchun, et al.
Publicado: (2023)

Regioselective Ni-Catalyzed reductive alkylsilylation of acrylonitrile with unactivated alkyl bromides and chlorosilanes
por: Sun, Jinwei, et al.
Publicado: (2022)

Ni-catalyzed 1,2-benzylboration of 1,2-disubstituted unactivated alkenes
por: Joung, Seewon, et al.
Publicado: (2019)

Ni-catalyzed carbamoylation of unactivated alkenes for stereoselective construction of six-membered lactams
por: Zhang, Chenhuan, et al.
Publicado: (2022)

Methodologies for the synthesis of quaternary carbon centers via hydroalkylation of unactivated olefins: twenty years of advances
por: Silva, Thiago S, et al.
Publicado: (2021)

Controllable access to trifluoromethyl-containing indoles and indolines: palladium-catalyzed regioselective functionalization of unactivated alkenes with trifluoroacetimidoyl chlorides
por: Yang, Hefei, et al.
Publicado: (2022)

Ni-catalyzed hydroalkylation of olefins with N-sulfonyl amines
por: Yan, Xiao-Biao, et al.
Publicado: (2021)

Enantioselective synthesis of α-aminoboronates by NiH-catalysed asymmetric hydroamidation of alkenyl boronates
por: Zhang, Yao, et al.
Publicado: (2022)

Ligand-modulated nickel-catalyzed regioselective silylalkylation of alkenes
por: Ding, Chao, et al.
Publicado: (2023)

Regioselective Hydroalkylation and Arylalkylation of Alkynes by Photoredox/Nickel Dual Catalysis: Application and Mechanism
por: Yue, Huifeng, et al.
Publicado: (2020)

Ni-Catalyzed Regioselective Reductive 1,3-Dialkenylation of Alkenes
por: Wickham, Laura M., et al.
Publicado: (2022)

Hydroalkylation of Aryl Alkenes with Organohalides Catalyzed by Molybdenum Oxido Based Lewis Pairs
por: Zwettler, Niklas, et al.
Publicado: (2020)

Alkyl halides as both hydride and alkyl sources in catalytic regioselective reductive olefin hydroalkylation
por: Chen, Xianxiao, et al.
Publicado: (2020)

Copper-catalyzed diamination of unactivated alkenes with hydroxylamines
por: Shen, Kun, et al.
Publicado: (2015)

Asymmetric Enzymatic Hydration of Unactivated, Aliphatic Alkenes
por: Demming, Rebecca M., et al.
Publicado: (2018)

2-Alkylation of 3-Alkyindoles With Unactivated Alkenes
por: Pan, Xuling, et al.
Publicado: (2022)

Metal-free electrochemical dihydroxylation of unactivated alkenes
por: Liu, Min, et al.
Publicado: (2023)

Iridium-Catalyzed Enantioselective Alkene Hydroalkylation via a Heteroaryl-Directed Enolization–Decarboxylation Sequence
por: Jing, Changcheng, et al.
Publicado: (2023)

Catalytic intramolecular aminoarylation of unactivated alkenes with aryl sulfonamides
por: Noten, Efrey A., et al.
Publicado: (2022)

Radical 1‐Fluorosulfonyl‐2‐alkynylation of Unactivated Alkenes
por: Frye, Nils Lennart, et al.
Publicado: (2022)

Isocyanides as Acceptor Groups in MHAT Reactions with Unactivated Alkenes
por: Puig, Jordi, et al.
Publicado: (2023)

Development of highly efficient platinum catalysts for hydroalkoxylation and hydroamination of unactivated alkenes
por: Zhou, Yali, et al.
Publicado: (2021)

Transition Metal-Free 1,2-Carboboration of Unactivated Alkenes
por: Cheng, Ying, et al.
Publicado: (2018)

A General Acid‐Mediated Hydroaminomethylation of Unactivated Alkenes and Alkynes
por: Kaiser, Daniel, et al.
Publicado: (2019)

Directed nickel-catalyzed regio- and diastereoselective arylamination of unactivated alkenes
por: Xie, Leipeng, et al.
Publicado: (2021)

Aldehyde-catalyzed epoxidation of unactivated alkenes with aqueous hydrogen peroxide
por: Triandafillidi, Ierasia, et al.
Publicado: (2021)

Nickel-catalyzed asymmetric reductive aryl-allylation of unactivated alkenes
por: Lin, Zhiyang, et al.
Publicado: (2021)

Nickel-Catalyzed 1,1-Aminoborylation of Unactivated Terminal Alkenes
por: Talavera, Laura, et al.
Publicado: (2023)

General acid-mediated aminolactone formation using unactivated alkenes
por: Just, David, et al.
Publicado: (2023)

Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp(3))–H bonds
por: Wu, Xinxin, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_6l72geuqlohg9uvhhbkm12thbt