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High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO(3) supercapacitor electrode

One of the most pressing concerns in today's power networks is ensuring that consumers (both home and industrial) have access to efficient and long-lasting economic energy. Due to improved power accessibility and high specific capacitance without deterioration over long working times, supercapa...

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Autores principales: Nasreen, Farah, Anwar, Abdul Waheed, Majeed, Abdul, Ahmad, Muhammad Ashfaq, Ilyas, Usman, Ahmad, Furqan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8996255/
https://www.ncbi.nlm.nih.gov/pubmed/35425034
http://dx.doi.org/10.1039/d1ra08413e
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author Nasreen, Farah
Anwar, Abdul Waheed
Majeed, Abdul
Ahmad, Muhammad Ashfaq
Ilyas, Usman
Ahmad, Furqan
author_facet Nasreen, Farah
Anwar, Abdul Waheed
Majeed, Abdul
Ahmad, Muhammad Ashfaq
Ilyas, Usman
Ahmad, Furqan
author_sort Nasreen, Farah
collection PubMed
description One of the most pressing concerns in today's power networks is ensuring that consumers (both home and industrial) have access to efficient and long-lasting economic energy. Due to improved power accessibility and high specific capacitance without deterioration over long working times, supercapacitor-based energy storage systems can be a viable solution to this problem. So, here, tungsten trioxide (WO(3)) nanocomposites containing reduced graphene oxide and carbon nanotubes i.e. (RGO-WO(3)), (CNT-WO(3)), and (RGO–CNT-WO(3)), as well as pure WO(3) nanostructures as electrode materials, were synthesized using a simple hydrothermal process. The monoclinic phase of WO(3) with high diffraction peaks is visible in X-ray diffraction analysis, indicating good crystallinity of all electrode materials. Nanoflowers of WO(3) were well-decorated on the RGO/CNTs conductive network in SEM micrographs. In a three-electrode system, the specific capacitance of the RGO–CNT-WO(3) electrode is 691.38 F g(−1) at 5 mV s(−1) and 633.3 F g(−1) at 2 A g(−1), which is significantly higher than that of pure WO(3) and other binary electrodes. Furthermore, at 2 A g(−1), it achieves a coulombic efficiency of 98.4%. After 5000 cycles, RGO–CNT-WO(3) retains 89.09% of its capacitance at 1000 mV s(−1), indicating a promising rate capability and good cycling stability performance.
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spelling pubmed-89962552022-04-13 High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO(3) supercapacitor electrode Nasreen, Farah Anwar, Abdul Waheed Majeed, Abdul Ahmad, Muhammad Ashfaq Ilyas, Usman Ahmad, Furqan RSC Adv Chemistry One of the most pressing concerns in today's power networks is ensuring that consumers (both home and industrial) have access to efficient and long-lasting economic energy. Due to improved power accessibility and high specific capacitance without deterioration over long working times, supercapacitor-based energy storage systems can be a viable solution to this problem. So, here, tungsten trioxide (WO(3)) nanocomposites containing reduced graphene oxide and carbon nanotubes i.e. (RGO-WO(3)), (CNT-WO(3)), and (RGO–CNT-WO(3)), as well as pure WO(3) nanostructures as electrode materials, were synthesized using a simple hydrothermal process. The monoclinic phase of WO(3) with high diffraction peaks is visible in X-ray diffraction analysis, indicating good crystallinity of all electrode materials. Nanoflowers of WO(3) were well-decorated on the RGO/CNTs conductive network in SEM micrographs. In a three-electrode system, the specific capacitance of the RGO–CNT-WO(3) electrode is 691.38 F g(−1) at 5 mV s(−1) and 633.3 F g(−1) at 2 A g(−1), which is significantly higher than that of pure WO(3) and other binary electrodes. Furthermore, at 2 A g(−1), it achieves a coulombic efficiency of 98.4%. After 5000 cycles, RGO–CNT-WO(3) retains 89.09% of its capacitance at 1000 mV s(−1), indicating a promising rate capability and good cycling stability performance. The Royal Society of Chemistry 2022-04-11 /pmc/articles/PMC8996255/ /pubmed/35425034 http://dx.doi.org/10.1039/d1ra08413e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Nasreen, Farah
Anwar, Abdul Waheed
Majeed, Abdul
Ahmad, Muhammad Ashfaq
Ilyas, Usman
Ahmad, Furqan
High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO(3) supercapacitor electrode
title High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO(3) supercapacitor electrode
title_full High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO(3) supercapacitor electrode
title_fullStr High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO(3) supercapacitor electrode
title_full_unstemmed High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO(3) supercapacitor electrode
title_short High performance and remarkable cyclic stability of a nanostructured RGO–CNT-WO(3) supercapacitor electrode
title_sort high performance and remarkable cyclic stability of a nanostructured rgo–cnt-wo(3) supercapacitor electrode
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8996255/
https://www.ncbi.nlm.nih.gov/pubmed/35425034
http://dx.doi.org/10.1039/d1ra08413e
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