Cargando…

Preparation of Boron/Sulfur-Codoped Porous Carbon Derived from Biological Wastes and Its Application in a Supercapacitor

Abundant biomass resources are a good choice for preparing electrode materials for supercapacitors, but developing a versatile and simple synthetic method to convert them into electrode materials remains a challenge. In the present research, our team reports a promising strategy and cost-efficient m...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Yanbin, Wang, Dian, Li, Zhaoxia, Su, Qiong, Wei, Shuai, Pang, Shaofeng, Zhao, Xiangfei, Liang, Lichun, Kang, Lihui, Cao, Shijun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000563/
https://www.ncbi.nlm.nih.gov/pubmed/35407301
http://dx.doi.org/10.3390/nano12071182
_version_ 1784685464941232128
author Wang, Yanbin
Wang, Dian
Li, Zhaoxia
Su, Qiong
Wei, Shuai
Pang, Shaofeng
Zhao, Xiangfei
Liang, Lichun
Kang, Lihui
Cao, Shijun
author_facet Wang, Yanbin
Wang, Dian
Li, Zhaoxia
Su, Qiong
Wei, Shuai
Pang, Shaofeng
Zhao, Xiangfei
Liang, Lichun
Kang, Lihui
Cao, Shijun
author_sort Wang, Yanbin
collection PubMed
description Abundant biomass resources are a good choice for preparing electrode materials for supercapacitors, but developing a versatile and simple synthetic method to convert them into electrode materials remains a challenge. In the present research, our team reports a promising strategy and cost-efficient method to fabricate boron/sulfur-codoped porous carbon from biomass sources, mainly utilizing four biomass materials. Detailed material characterization showed that the samples produced by this approach possess rich B and S doping. Additionally, the original biomass materials treated by activation produce abundant pores. Therefore, owing to the synergetic effect of abundant atomic doping and microporous/mesoporous distribution, the obtained carbon as electrode material manifested excellent specific capacitances of 290 F g(−1) at a 0.5 A g(−1) current density. Moreover, the specific energy of the prepared samples of the as-assembled symmetric supercapacitor is as high as 16.65 Wh kg(−1) in 1 M Na(2)SO(4), with a brilliant cyclical performance of only a 2.91% capacitance decay over 10,000 cycles. In addition, it has been verified universally that three other types of bio-wastes can also prepare electrode material using this method. This paper represents a significant attempt to turn waste biomass into treasure while also providing ideas for the design and preparation of supercapacitor electrode materials.
format Online
Article
Text
id pubmed-9000563
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-90005632022-04-12 Preparation of Boron/Sulfur-Codoped Porous Carbon Derived from Biological Wastes and Its Application in a Supercapacitor Wang, Yanbin Wang, Dian Li, Zhaoxia Su, Qiong Wei, Shuai Pang, Shaofeng Zhao, Xiangfei Liang, Lichun Kang, Lihui Cao, Shijun Nanomaterials (Basel) Article Abundant biomass resources are a good choice for preparing electrode materials for supercapacitors, but developing a versatile and simple synthetic method to convert them into electrode materials remains a challenge. In the present research, our team reports a promising strategy and cost-efficient method to fabricate boron/sulfur-codoped porous carbon from biomass sources, mainly utilizing four biomass materials. Detailed material characterization showed that the samples produced by this approach possess rich B and S doping. Additionally, the original biomass materials treated by activation produce abundant pores. Therefore, owing to the synergetic effect of abundant atomic doping and microporous/mesoporous distribution, the obtained carbon as electrode material manifested excellent specific capacitances of 290 F g(−1) at a 0.5 A g(−1) current density. Moreover, the specific energy of the prepared samples of the as-assembled symmetric supercapacitor is as high as 16.65 Wh kg(−1) in 1 M Na(2)SO(4), with a brilliant cyclical performance of only a 2.91% capacitance decay over 10,000 cycles. In addition, it has been verified universally that three other types of bio-wastes can also prepare electrode material using this method. This paper represents a significant attempt to turn waste biomass into treasure while also providing ideas for the design and preparation of supercapacitor electrode materials. MDPI 2022-04-01 /pmc/articles/PMC9000563/ /pubmed/35407301 http://dx.doi.org/10.3390/nano12071182 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wang, Yanbin
Wang, Dian
Li, Zhaoxia
Su, Qiong
Wei, Shuai
Pang, Shaofeng
Zhao, Xiangfei
Liang, Lichun
Kang, Lihui
Cao, Shijun
Preparation of Boron/Sulfur-Codoped Porous Carbon Derived from Biological Wastes and Its Application in a Supercapacitor
title Preparation of Boron/Sulfur-Codoped Porous Carbon Derived from Biological Wastes and Its Application in a Supercapacitor
title_full Preparation of Boron/Sulfur-Codoped Porous Carbon Derived from Biological Wastes and Its Application in a Supercapacitor
title_fullStr Preparation of Boron/Sulfur-Codoped Porous Carbon Derived from Biological Wastes and Its Application in a Supercapacitor
title_full_unstemmed Preparation of Boron/Sulfur-Codoped Porous Carbon Derived from Biological Wastes and Its Application in a Supercapacitor
title_short Preparation of Boron/Sulfur-Codoped Porous Carbon Derived from Biological Wastes and Its Application in a Supercapacitor
title_sort preparation of boron/sulfur-codoped porous carbon derived from biological wastes and its application in a supercapacitor
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000563/
https://www.ncbi.nlm.nih.gov/pubmed/35407301
http://dx.doi.org/10.3390/nano12071182
work_keys_str_mv AT wangyanbin preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT wangdian preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT lizhaoxia preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT suqiong preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT weishuai preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT pangshaofeng preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT zhaoxiangfei preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT lianglichun preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT kanglihui preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor
AT caoshijun preparationofboronsulfurcodopedporouscarbonderivedfrombiologicalwastesanditsapplicationinasupercapacitor