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Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries

Sn is a promising candidate anode material with a high theoretical capacity (994 mAh/g). However, the drastic structural changes of Sn particles caused by their pulverization and aggregation during charge–discharge cycling reduce their capacity over time. To overcome this, a TiNi shape memory alloy...

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Autores principales: Seo, Duck-Hyeon, Lee, Jun-Seok, Yun, Sang-Du, Yang, Jeong-Hyeon, Huh, Sun-Chul, Sung, Yon-Mo, Jeong, Hyo-Min, Noh, Jung-Pil
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000761/
https://www.ncbi.nlm.nih.gov/pubmed/35407997
http://dx.doi.org/10.3390/ma15072665
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author Seo, Duck-Hyeon
Lee, Jun-Seok
Yun, Sang-Du
Yang, Jeong-Hyeon
Huh, Sun-Chul
Sung, Yon-Mo
Jeong, Hyo-Min
Noh, Jung-Pil
author_facet Seo, Duck-Hyeon
Lee, Jun-Seok
Yun, Sang-Du
Yang, Jeong-Hyeon
Huh, Sun-Chul
Sung, Yon-Mo
Jeong, Hyo-Min
Noh, Jung-Pil
author_sort Seo, Duck-Hyeon
collection PubMed
description Sn is a promising candidate anode material with a high theoretical capacity (994 mAh/g). However, the drastic structural changes of Sn particles caused by their pulverization and aggregation during charge–discharge cycling reduce their capacity over time. To overcome this, a TiNi shape memory alloy (SMA) was introduced as a buffer matrix. Sn/TiNi SMA multilayer thin films were deposited on Cu foil using a DC magnetron sputtering system. When the TiNi alloy was employed at the bottom of a Sn thin film, it did not adequately buffer the volume changes and internal stress of Sn, and stress absorption was not evident. However, an electrode with an additional top layer of room-temperature-deposition TiNi (TiNi(RT)) lost capacity much more slowly than the Sn or Sn/TiNi electrodes, retaining 50% capacity up to 40 cycles. Moreover, the charge-transfer resistance decreased from 318.1 Ω after one cycle to 246.1 Ω after twenty. The improved cycle performance indicates that the TiNi(RT) and TiNi-alloy thin films overall held the Sn thin film. The structure was changed so that Li and Sn reacted well; the stress-absorption effect was observed in the TiNi SMA thin films.
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spelling pubmed-90007612022-04-12 Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries Seo, Duck-Hyeon Lee, Jun-Seok Yun, Sang-Du Yang, Jeong-Hyeon Huh, Sun-Chul Sung, Yon-Mo Jeong, Hyo-Min Noh, Jung-Pil Materials (Basel) Article Sn is a promising candidate anode material with a high theoretical capacity (994 mAh/g). However, the drastic structural changes of Sn particles caused by their pulverization and aggregation during charge–discharge cycling reduce their capacity over time. To overcome this, a TiNi shape memory alloy (SMA) was introduced as a buffer matrix. Sn/TiNi SMA multilayer thin films were deposited on Cu foil using a DC magnetron sputtering system. When the TiNi alloy was employed at the bottom of a Sn thin film, it did not adequately buffer the volume changes and internal stress of Sn, and stress absorption was not evident. However, an electrode with an additional top layer of room-temperature-deposition TiNi (TiNi(RT)) lost capacity much more slowly than the Sn or Sn/TiNi electrodes, retaining 50% capacity up to 40 cycles. Moreover, the charge-transfer resistance decreased from 318.1 Ω after one cycle to 246.1 Ω after twenty. The improved cycle performance indicates that the TiNi(RT) and TiNi-alloy thin films overall held the Sn thin film. The structure was changed so that Li and Sn reacted well; the stress-absorption effect was observed in the TiNi SMA thin films. MDPI 2022-04-05 /pmc/articles/PMC9000761/ /pubmed/35407997 http://dx.doi.org/10.3390/ma15072665 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Seo, Duck-Hyeon
Lee, Jun-Seok
Yun, Sang-Du
Yang, Jeong-Hyeon
Huh, Sun-Chul
Sung, Yon-Mo
Jeong, Hyo-Min
Noh, Jung-Pil
Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries
title Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries
title_full Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries
title_fullStr Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries
title_full_unstemmed Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries
title_short Electrochemical Properties of Multilayered Sn/TiNi Shape-Memory-Alloy Thin-Film Electrodes for High-Performance Anodes in Li-Ion Batteries
title_sort electrochemical properties of multilayered sn/tini shape-memory-alloy thin-film electrodes for high-performance anodes in li-ion batteries
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000761/
https://www.ncbi.nlm.nih.gov/pubmed/35407997
http://dx.doi.org/10.3390/ma15072665
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