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The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study
The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd(...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000884/ https://www.ncbi.nlm.nih.gov/pubmed/35407178 http://dx.doi.org/10.3390/nano12071060 |
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author | El-Sayed, Fatma Hussien, Mai S. A. Mohammed, Mervat I. Ganesh, Vanga AlAbdulaal, Thekrayat H. Zahran, Heba Y. Yahia, Ibrahim S. Hegazy, Hosam H. Abdel-wahab, Mohamed Sh. Shkir, Mohd. Valarasu, Santiyagu Ibrahim, Medhat A. |
author_facet | El-Sayed, Fatma Hussien, Mai S. A. Mohammed, Mervat I. Ganesh, Vanga AlAbdulaal, Thekrayat H. Zahran, Heba Y. Yahia, Ibrahim S. Hegazy, Hosam H. Abdel-wahab, Mohamed Sh. Shkir, Mohd. Valarasu, Santiyagu Ibrahim, Medhat A. |
author_sort | El-Sayed, Fatma |
collection | PubMed |
description | The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd(2)O(3) doped CuO) nanoparticles by combustion method for effective degradation of dye, methylene blue (MB). X-ray diffraction (XRD), Field emission Scanning electron microscopy (FESEM), Zeta potential have been applied for characterization. Photocatalyst validity has been evaluated for methylene blue degradation (MB). Test conditions such as time of contact, H(2)O(2), pH, and photo-Fenton have been modified to identify optimal degradation conditions. Noticeably, 7.5% Nd(2)O(3) doped CuO nanoparticle demonstrated the highest photocatalytic efficiency, up to 90.8% in 80 min, with a 0.0227 min(−1) degradation rate. However, the photocatalytic efficiency at pH 10 becomes 99% with a rate constant of 0.082 min(−1). Cyclic experiments showed the Nd(2)O(3) doped CuO nanoparticle’s stability over repeated use. Scavenge hydroxyl radical species responsible for degradation using 7.5% Nd(2)O(3) doped CuO nanoparticles have been investigated under visible irradiation. |
format | Online Article Text |
id | pubmed-9000884 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-90008842022-04-12 The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study El-Sayed, Fatma Hussien, Mai S. A. Mohammed, Mervat I. Ganesh, Vanga AlAbdulaal, Thekrayat H. Zahran, Heba Y. Yahia, Ibrahim S. Hegazy, Hosam H. Abdel-wahab, Mohamed Sh. Shkir, Mohd. Valarasu, Santiyagu Ibrahim, Medhat A. Nanomaterials (Basel) Article The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd(2)O(3) doped CuO) nanoparticles by combustion method for effective degradation of dye, methylene blue (MB). X-ray diffraction (XRD), Field emission Scanning electron microscopy (FESEM), Zeta potential have been applied for characterization. Photocatalyst validity has been evaluated for methylene blue degradation (MB). Test conditions such as time of contact, H(2)O(2), pH, and photo-Fenton have been modified to identify optimal degradation conditions. Noticeably, 7.5% Nd(2)O(3) doped CuO nanoparticle demonstrated the highest photocatalytic efficiency, up to 90.8% in 80 min, with a 0.0227 min(−1) degradation rate. However, the photocatalytic efficiency at pH 10 becomes 99% with a rate constant of 0.082 min(−1). Cyclic experiments showed the Nd(2)O(3) doped CuO nanoparticle’s stability over repeated use. Scavenge hydroxyl radical species responsible for degradation using 7.5% Nd(2)O(3) doped CuO nanoparticles have been investigated under visible irradiation. MDPI 2022-03-24 /pmc/articles/PMC9000884/ /pubmed/35407178 http://dx.doi.org/10.3390/nano12071060 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article El-Sayed, Fatma Hussien, Mai S. A. Mohammed, Mervat I. Ganesh, Vanga AlAbdulaal, Thekrayat H. Zahran, Heba Y. Yahia, Ibrahim S. Hegazy, Hosam H. Abdel-wahab, Mohamed Sh. Shkir, Mohd. Valarasu, Santiyagu Ibrahim, Medhat A. The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study |
title | The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study |
title_full | The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study |
title_fullStr | The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study |
title_full_unstemmed | The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study |
title_short | The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study |
title_sort | photocatalytic performance of nd(2)o(3) doped cuo nanoparticles with enhanced methylene blue degradation: synthesis, characterization and comparative study |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000884/ https://www.ncbi.nlm.nih.gov/pubmed/35407178 http://dx.doi.org/10.3390/nano12071060 |
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