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The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study

The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd(...

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Autores principales: El-Sayed, Fatma, Hussien, Mai S. A., Mohammed, Mervat I., Ganesh, Vanga, AlAbdulaal, Thekrayat H., Zahran, Heba Y., Yahia, Ibrahim S., Hegazy, Hosam H., Abdel-wahab, Mohamed Sh., Shkir, Mohd., Valarasu, Santiyagu, Ibrahim, Medhat A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000884/
https://www.ncbi.nlm.nih.gov/pubmed/35407178
http://dx.doi.org/10.3390/nano12071060
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author El-Sayed, Fatma
Hussien, Mai S. A.
Mohammed, Mervat I.
Ganesh, Vanga
AlAbdulaal, Thekrayat H.
Zahran, Heba Y.
Yahia, Ibrahim S.
Hegazy, Hosam H.
Abdel-wahab, Mohamed Sh.
Shkir, Mohd.
Valarasu, Santiyagu
Ibrahim, Medhat A.
author_facet El-Sayed, Fatma
Hussien, Mai S. A.
Mohammed, Mervat I.
Ganesh, Vanga
AlAbdulaal, Thekrayat H.
Zahran, Heba Y.
Yahia, Ibrahim S.
Hegazy, Hosam H.
Abdel-wahab, Mohamed Sh.
Shkir, Mohd.
Valarasu, Santiyagu
Ibrahim, Medhat A.
author_sort El-Sayed, Fatma
collection PubMed
description The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd(2)O(3) doped CuO) nanoparticles by combustion method for effective degradation of dye, methylene blue (MB). X-ray diffraction (XRD), Field emission Scanning electron microscopy (FESEM), Zeta potential have been applied for characterization. Photocatalyst validity has been evaluated for methylene blue degradation (MB). Test conditions such as time of contact, H(2)O(2), pH, and photo-Fenton have been modified to identify optimal degradation conditions. Noticeably, 7.5% Nd(2)O(3) doped CuO nanoparticle demonstrated the highest photocatalytic efficiency, up to 90.8% in 80 min, with a 0.0227 min(−1) degradation rate. However, the photocatalytic efficiency at pH 10 becomes 99% with a rate constant of 0.082 min(−1). Cyclic experiments showed the Nd(2)O(3) doped CuO nanoparticle’s stability over repeated use. Scavenge hydroxyl radical species responsible for degradation using 7.5% Nd(2)O(3) doped CuO nanoparticles have been investigated under visible irradiation.
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spelling pubmed-90008842022-04-12 The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study El-Sayed, Fatma Hussien, Mai S. A. Mohammed, Mervat I. Ganesh, Vanga AlAbdulaal, Thekrayat H. Zahran, Heba Y. Yahia, Ibrahim S. Hegazy, Hosam H. Abdel-wahab, Mohamed Sh. Shkir, Mohd. Valarasu, Santiyagu Ibrahim, Medhat A. Nanomaterials (Basel) Article The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd(2)O(3) doped CuO) nanoparticles by combustion method for effective degradation of dye, methylene blue (MB). X-ray diffraction (XRD), Field emission Scanning electron microscopy (FESEM), Zeta potential have been applied for characterization. Photocatalyst validity has been evaluated for methylene blue degradation (MB). Test conditions such as time of contact, H(2)O(2), pH, and photo-Fenton have been modified to identify optimal degradation conditions. Noticeably, 7.5% Nd(2)O(3) doped CuO nanoparticle demonstrated the highest photocatalytic efficiency, up to 90.8% in 80 min, with a 0.0227 min(−1) degradation rate. However, the photocatalytic efficiency at pH 10 becomes 99% with a rate constant of 0.082 min(−1). Cyclic experiments showed the Nd(2)O(3) doped CuO nanoparticle’s stability over repeated use. Scavenge hydroxyl radical species responsible for degradation using 7.5% Nd(2)O(3) doped CuO nanoparticles have been investigated under visible irradiation. MDPI 2022-03-24 /pmc/articles/PMC9000884/ /pubmed/35407178 http://dx.doi.org/10.3390/nano12071060 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
El-Sayed, Fatma
Hussien, Mai S. A.
Mohammed, Mervat I.
Ganesh, Vanga
AlAbdulaal, Thekrayat H.
Zahran, Heba Y.
Yahia, Ibrahim S.
Hegazy, Hosam H.
Abdel-wahab, Mohamed Sh.
Shkir, Mohd.
Valarasu, Santiyagu
Ibrahim, Medhat A.
The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study
title The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study
title_full The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study
title_fullStr The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study
title_full_unstemmed The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study
title_short The Photocatalytic Performance of Nd(2)O(3) Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study
title_sort photocatalytic performance of nd(2)o(3) doped cuo nanoparticles with enhanced methylene blue degradation: synthesis, characterization and comparative study
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9000884/
https://www.ncbi.nlm.nih.gov/pubmed/35407178
http://dx.doi.org/10.3390/nano12071060
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