Cargando…

Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance

In this study, multilayer graphene oxide (GO) was used to prepare the functional layer of polyimide/GO composite membrane with polyimide (P84) used as the supporting layer. Chitosan added in the functional layer was utilized to adjust the selectivity of the composite membrane. The effects of GO and...

Descripción completa

Detalles Bibliográficos
Autores principales: Han, Runlin, Wu, Kui, Xu, Lingfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9002502/
https://www.ncbi.nlm.nih.gov/pubmed/35406229
http://dx.doi.org/10.3390/polym14071353
_version_ 1784685905591664640
author Han, Runlin
Wu, Kui
Xu, Lingfeng
author_facet Han, Runlin
Wu, Kui
Xu, Lingfeng
author_sort Han, Runlin
collection PubMed
description In this study, multilayer graphene oxide (GO) was used to prepare the functional layer of polyimide/GO composite membrane with polyimide (P84) used as the supporting layer. Chitosan added in the functional layer was utilized to adjust the selectivity of the composite membrane. The effects of GO and chitosan contents on membrane morphology and separation performance were investigated in detail. The composite membrane showed high rejection to Congo red and Methyl orange with high flux but low rejection to Na(2)SO(4) and MgCl(2) at 0.2 MPa and ambient temperature. The membrane exhibited excellent solvent resistance in N,N-dimethylacetamide (DMAc) after being crosslinked with 0.5 wt.% triethylene tetramine. The result means that a highly selective and solvent-resistant P84/GO composite membrane was prepared with the facile filtration preparation method.
format Online
Article
Text
id pubmed-9002502
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-90025022022-04-13 Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance Han, Runlin Wu, Kui Xu, Lingfeng Polymers (Basel) Communication In this study, multilayer graphene oxide (GO) was used to prepare the functional layer of polyimide/GO composite membrane with polyimide (P84) used as the supporting layer. Chitosan added in the functional layer was utilized to adjust the selectivity of the composite membrane. The effects of GO and chitosan contents on membrane morphology and separation performance were investigated in detail. The composite membrane showed high rejection to Congo red and Methyl orange with high flux but low rejection to Na(2)SO(4) and MgCl(2) at 0.2 MPa and ambient temperature. The membrane exhibited excellent solvent resistance in N,N-dimethylacetamide (DMAc) after being crosslinked with 0.5 wt.% triethylene tetramine. The result means that a highly selective and solvent-resistant P84/GO composite membrane was prepared with the facile filtration preparation method. MDPI 2022-03-27 /pmc/articles/PMC9002502/ /pubmed/35406229 http://dx.doi.org/10.3390/polym14071353 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Han, Runlin
Wu, Kui
Xu, Lingfeng
Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance
title Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance
title_full Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance
title_fullStr Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance
title_full_unstemmed Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance
title_short Facile Preparation of Loose P84 Copolyimide/GO Composite Membrane with Excellent Selectivity and Solvent Resistance
title_sort facile preparation of loose p84 copolyimide/go composite membrane with excellent selectivity and solvent resistance
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9002502/
https://www.ncbi.nlm.nih.gov/pubmed/35406229
http://dx.doi.org/10.3390/polym14071353
work_keys_str_mv AT hanrunlin facilepreparationofloosep84copolyimidegocompositemembranewithexcellentselectivityandsolventresistance
AT wukui facilepreparationofloosep84copolyimidegocompositemembranewithexcellentselectivityandsolventresistance
AT xulingfeng facilepreparationofloosep84copolyimidegocompositemembranewithexcellentselectivityandsolventresistance