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Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol

Recently, the use of metal oxides as inexpensive and efficient catalysts has been considered by researchers. In this work, we introduce a new nanocatalyst including a mixed metal oxide, consisting of manganese oxide, cerium oxide, and reduced graphene oxide (Mn(3)O(4)-CeO(2)-rGO) by the hydrothermal...

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Detalles Bibliográficos
Autores principales: Askari, Mohammad Bagher, Rozati, Seyed Mohammad, Di Bartolomeo, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9002773/
https://www.ncbi.nlm.nih.gov/pubmed/35407306
http://dx.doi.org/10.3390/nano12071187
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author Askari, Mohammad Bagher
Rozati, Seyed Mohammad
Di Bartolomeo, Antonio
author_facet Askari, Mohammad Bagher
Rozati, Seyed Mohammad
Di Bartolomeo, Antonio
author_sort Askari, Mohammad Bagher
collection PubMed
description Recently, the use of metal oxides as inexpensive and efficient catalysts has been considered by researchers. In this work, we introduce a new nanocatalyst including a mixed metal oxide, consisting of manganese oxide, cerium oxide, and reduced graphene oxide (Mn(3)O(4)-CeO(2)-rGO) by the hydrothermal method. The synthesized nanocatalyst was evaluated for the methanol oxidation reaction. The synergetic effect of metal oxides on the surface of rGO was investigated. Mn(3)O(4)-CeO(2)-rGO showed an oxidation current density of 17.7 mA/cm(2) in overpotential of 0.51 V and 91% stability after 500 consecutive rounds of cyclic voltammetry. According to these results, the synthesized nanocatalyst can be an attractive and efficient option in the methanol oxidation reaction process.
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spelling pubmed-90027732022-04-13 Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol Askari, Mohammad Bagher Rozati, Seyed Mohammad Di Bartolomeo, Antonio Nanomaterials (Basel) Article Recently, the use of metal oxides as inexpensive and efficient catalysts has been considered by researchers. In this work, we introduce a new nanocatalyst including a mixed metal oxide, consisting of manganese oxide, cerium oxide, and reduced graphene oxide (Mn(3)O(4)-CeO(2)-rGO) by the hydrothermal method. The synthesized nanocatalyst was evaluated for the methanol oxidation reaction. The synergetic effect of metal oxides on the surface of rGO was investigated. Mn(3)O(4)-CeO(2)-rGO showed an oxidation current density of 17.7 mA/cm(2) in overpotential of 0.51 V and 91% stability after 500 consecutive rounds of cyclic voltammetry. According to these results, the synthesized nanocatalyst can be an attractive and efficient option in the methanol oxidation reaction process. MDPI 2022-04-02 /pmc/articles/PMC9002773/ /pubmed/35407306 http://dx.doi.org/10.3390/nano12071187 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Askari, Mohammad Bagher
Rozati, Seyed Mohammad
Di Bartolomeo, Antonio
Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol
title Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol
title_full Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol
title_fullStr Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol
title_full_unstemmed Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol
title_short Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol
title_sort fabrication of mn(3)o(4)-ceo(2)-rgo as nanocatalyst for electro-oxidation of methanol
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9002773/
https://www.ncbi.nlm.nih.gov/pubmed/35407306
http://dx.doi.org/10.3390/nano12071187
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