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Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol
Recently, the use of metal oxides as inexpensive and efficient catalysts has been considered by researchers. In this work, we introduce a new nanocatalyst including a mixed metal oxide, consisting of manganese oxide, cerium oxide, and reduced graphene oxide (Mn(3)O(4)-CeO(2)-rGO) by the hydrothermal...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9002773/ https://www.ncbi.nlm.nih.gov/pubmed/35407306 http://dx.doi.org/10.3390/nano12071187 |
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author | Askari, Mohammad Bagher Rozati, Seyed Mohammad Di Bartolomeo, Antonio |
author_facet | Askari, Mohammad Bagher Rozati, Seyed Mohammad Di Bartolomeo, Antonio |
author_sort | Askari, Mohammad Bagher |
collection | PubMed |
description | Recently, the use of metal oxides as inexpensive and efficient catalysts has been considered by researchers. In this work, we introduce a new nanocatalyst including a mixed metal oxide, consisting of manganese oxide, cerium oxide, and reduced graphene oxide (Mn(3)O(4)-CeO(2)-rGO) by the hydrothermal method. The synthesized nanocatalyst was evaluated for the methanol oxidation reaction. The synergetic effect of metal oxides on the surface of rGO was investigated. Mn(3)O(4)-CeO(2)-rGO showed an oxidation current density of 17.7 mA/cm(2) in overpotential of 0.51 V and 91% stability after 500 consecutive rounds of cyclic voltammetry. According to these results, the synthesized nanocatalyst can be an attractive and efficient option in the methanol oxidation reaction process. |
format | Online Article Text |
id | pubmed-9002773 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-90027732022-04-13 Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol Askari, Mohammad Bagher Rozati, Seyed Mohammad Di Bartolomeo, Antonio Nanomaterials (Basel) Article Recently, the use of metal oxides as inexpensive and efficient catalysts has been considered by researchers. In this work, we introduce a new nanocatalyst including a mixed metal oxide, consisting of manganese oxide, cerium oxide, and reduced graphene oxide (Mn(3)O(4)-CeO(2)-rGO) by the hydrothermal method. The synthesized nanocatalyst was evaluated for the methanol oxidation reaction. The synergetic effect of metal oxides on the surface of rGO was investigated. Mn(3)O(4)-CeO(2)-rGO showed an oxidation current density of 17.7 mA/cm(2) in overpotential of 0.51 V and 91% stability after 500 consecutive rounds of cyclic voltammetry. According to these results, the synthesized nanocatalyst can be an attractive and efficient option in the methanol oxidation reaction process. MDPI 2022-04-02 /pmc/articles/PMC9002773/ /pubmed/35407306 http://dx.doi.org/10.3390/nano12071187 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Askari, Mohammad Bagher Rozati, Seyed Mohammad Di Bartolomeo, Antonio Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol |
title | Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol |
title_full | Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol |
title_fullStr | Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol |
title_full_unstemmed | Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol |
title_short | Fabrication of Mn(3)O(4)-CeO(2)-rGO as Nanocatalyst for Electro-Oxidation of Methanol |
title_sort | fabrication of mn(3)o(4)-ceo(2)-rgo as nanocatalyst for electro-oxidation of methanol |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9002773/ https://www.ncbi.nlm.nih.gov/pubmed/35407306 http://dx.doi.org/10.3390/nano12071187 |
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