Amplification of weak chiral inductions for excellent control over the helical orientation of discrete topologically chiral (M(3)L(2))(n) polyhedra

Superb control over the helical chirality of discrete (M(3)L(2))(n) polyhedra (n = 2,4,8, M = Cu(I) or Ag(I)) created from the self-assembly of propeller-shaped ligands (L) equipped with chiral side chains is demonstrated here. Almost perfect chiral induction (>99 : 1) of the helical orientation...

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Detalles Bibliográficos
Autores principales: Domoto, Yuya, Yamamoto, Kidai, Horie, Shumpei, Yu, Zhengsu, Fujita, Makoto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9006968/
https://www.ncbi.nlm.nih.gov/pubmed/35509455
http://dx.doi.org/10.1039/d2sc00111j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9006968/
https://www.ncbi.nlm.nih.gov/pubmed/35509455
http://dx.doi.org/10.1039/d2sc00111j

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