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Amplification of weak chiral inductions for excellent control over the helical orientation of discrete topologically chiral (M(3)L(2))(n) polyhedra
Superb control over the helical chirality of discrete (M(3)L(2))(n) polyhedra (n = 2,4,8, M = Cu(I) or Ag(I)) created from the self-assembly of propeller-shaped ligands (L) equipped with chiral side chains is demonstrated here. Almost perfect chiral induction (>99 : 1) of the helical orientation...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9006968/ https://www.ncbi.nlm.nih.gov/pubmed/35509455 http://dx.doi.org/10.1039/d2sc00111j |