Iron(II) Complexes of 4-(Alkyldisulfanyl)-2,6-di(pyrazolyl)pyridine Derivatives. Correlation of Spin-Crossover Cooperativity with Molecular Structure Following Single-Crystal-to-Single-Crystal Desolvation

[Image: see text] The complex salts [Fe(L(1))(2)]X(2) (1X(2); L(1) = 4-(isopropyldisulfanyl)-2,6-bis(pyrazolyl)pyridine; X(–) = BF(4)(–), ClO(4)(–)) form solvated crystals from common organic solvents. Crystals of 1X(2)·Me(2)CO show abrupt spin transitions near 160 K, with up to 22 K thermal hystere...

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Detalles Bibliográficos
Autores principales: Kulmaczewski, Rafal, Kershaw Cook, Laurence J., Pask, Christopher M., Cespedes, Oscar, Halcrow, Malcolm A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9007408/
https://www.ncbi.nlm.nih.gov/pubmed/35431660
http://dx.doi.org/10.1021/acs.cgd.2c00005

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