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Synthesis of ultrahigh-molecular-weight ethylene/1-octene copolymers with salalen titanium(iv) complexes activated by methyaluminoxane

Two salalen titanium(iv) complexes ((H-salalen)TiCl(2) and (F-salalen)TiCl(2)) containing hydrogen and fluorine respectively on the phenolate ring close to the imine were synthesized for the copolymerization of ethylene with 1-octene to prepare poly(ethylene-co-1-octene) in the presence of methylalu...

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Detalles Bibliográficos
Autores principales: Zou, Baokang, Zhan, Yipeng, Xie, Xiuli, Zhang, TongTong, Qiu, Runkai, Zhu, Fangming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9010129/
https://www.ncbi.nlm.nih.gov/pubmed/35481088
http://dx.doi.org/10.1039/d2ra00165a