Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination

BACKGROUND: A zirconium-based metal-organic framework (Zr-MOF), named MOF-808, was synthesized and fully characterized by solvo-thermal method and functionalized by isonicotinic acid and employed as an efficient adsorbent for selective extraction and preconcentration of uranyl ions from water and wa...

Descripción completa

Detalles Bibliográficos
Autores principales: Sharifi-Rad, Marzieh, Kaykhaii, Massoud, Khajeh, Mostafa, Oveisi, Alireza
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer International Publishing 2022
Materias:
Research
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9013465/
https://www.ncbi.nlm.nih.gov/pubmed/35429981
http://dx.doi.org/10.1186/s13065-022-00821-1
_version_ 1784688000995688448
author Sharifi-Rad, Marzieh
Kaykhaii, Massoud
Khajeh, Mostafa
Oveisi, Alireza
author_facet Sharifi-Rad, Marzieh
Kaykhaii, Massoud
Khajeh, Mostafa
Oveisi, Alireza
author_sort Sharifi-Rad, Marzieh
collection PubMed
description BACKGROUND: A zirconium-based metal-organic framework (Zr-MOF), named MOF-808, was synthesized and fully characterized by solvo-thermal method and functionalized by isonicotinic acid and employed as an efficient adsorbent for selective extraction and preconcentration of uranyl ions from water and waste water samples in a batch solid phase extraction. RESULTS: Parameters affecting extraction such as volume and pH of the sample solution, the amount of sorbent, type and volume of eluting solvent, and adsorption and desorption times were investigated and optimized. Under the optimized conditions, high extraction efficiency was observed with a limit of detection of 0.9 µg L(− 1) for uranyl ions and relative standard deviations were found to be better than 2.1% in the range of 0.07–1000 µg L(− 1). CONCLUSIONS: These results indicated that the above procedure is fast, inexpensive, effective, reliable, applicable and organic solvent-free and showed the highly performance and stability of the Zr-MOF in SPE based analytical techniques.
format Online
Article
Text
id pubmed-9013465
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher Springer International Publishing
record_format MEDLINE/PubMed
spelling pubmed-90134652022-04-18 Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination Sharifi-Rad, Marzieh Kaykhaii, Massoud Khajeh, Mostafa Oveisi, Alireza BMC Chem Research BACKGROUND: A zirconium-based metal-organic framework (Zr-MOF), named MOF-808, was synthesized and fully characterized by solvo-thermal method and functionalized by isonicotinic acid and employed as an efficient adsorbent for selective extraction and preconcentration of uranyl ions from water and waste water samples in a batch solid phase extraction. RESULTS: Parameters affecting extraction such as volume and pH of the sample solution, the amount of sorbent, type and volume of eluting solvent, and adsorption and desorption times were investigated and optimized. Under the optimized conditions, high extraction efficiency was observed with a limit of detection of 0.9 µg L(− 1) for uranyl ions and relative standard deviations were found to be better than 2.1% in the range of 0.07–1000 µg L(− 1). CONCLUSIONS: These results indicated that the above procedure is fast, inexpensive, effective, reliable, applicable and organic solvent-free and showed the highly performance and stability of the Zr-MOF in SPE based analytical techniques. Springer International Publishing 2022-04-16 /pmc/articles/PMC9013465/ /pubmed/35429981 http://dx.doi.org/10.1186/s13065-022-00821-1 Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . The Creative Commons Public Domain Dedication waiver (http://creativecommons.org/publicdomain/zero/1.0/ (https://creativecommons.org/publicdomain/zero/1.0/) ) applies to the data made available in this article, unless otherwise stated in a credit line to the data.
spellingShingle Research
Sharifi-Rad, Marzieh
Kaykhaii, Massoud
Khajeh, Mostafa
Oveisi, Alireza
Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination
title Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination
title_full Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination
title_fullStr Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination
title_full_unstemmed Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination
title_short Synthesis, characterization and application of a zirconium-based MOF-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(VI) from wastewater prior to its spectrophotometric determination
title_sort synthesis, characterization and application of a zirconium-based mof-808 functionalized with isonicotinic acid for fast and efficient solid phase extraction of uranium(vi) from wastewater prior to its spectrophotometric determination
topic Research
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9013465/
https://www.ncbi.nlm.nih.gov/pubmed/35429981
http://dx.doi.org/10.1186/s13065-022-00821-1
work_keys_str_mv AT sharifiradmarzieh synthesischaracterizationandapplicationofazirconiumbasedmof808functionalizedwithisonicotinicacidforfastandefficientsolidphaseextractionofuraniumvifromwastewaterpriortoitsspectrophotometricdetermination
AT kaykhaiimassoud synthesischaracterizationandapplicationofazirconiumbasedmof808functionalizedwithisonicotinicacidforfastandefficientsolidphaseextractionofuraniumvifromwastewaterpriortoitsspectrophotometricdetermination
AT khajehmostafa synthesischaracterizationandapplicationofazirconiumbasedmof808functionalizedwithisonicotinicacidforfastandefficientsolidphaseextractionofuraniumvifromwastewaterpriortoitsspectrophotometricdetermination
AT oveisialireza synthesischaracterizationandapplicationofazirconiumbasedmof808functionalizedwithisonicotinicacidforfastandefficientsolidphaseextractionofuraniumvifromwastewaterpriortoitsspectrophotometricdetermination

Ejemplares similares