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Chemoenzymatic Hunsdiecker-Type Decarboxylative Bromination of Cinnamic Acids

[Image: see text] In this contribution, we report chemoenzymatic bromodecarboxylation (Hunsdiecker-type) of α,ß-unsaturated carboxylic acids. The extraordinarily robust chloroperoxidase from Curvularia inaequalis (CiVCPO) generated hypobromite from H(2)O(2) and bromide, which then spontaneously reac...

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Detalles Bibliográficos
Autores principales: Li, Huanhuan, Younes, Sabry H. H., Chen, Shaohang, Duan, Peigao, Cui, Chengsen, Wever, Ron, Zhang, Wuyuan, Hollmann, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9016706/
https://www.ncbi.nlm.nih.gov/pubmed/35465241
http://dx.doi.org/10.1021/acscatal.2c00485