Surprises in the Solvent-Induced Self-Ionization in the Uranium Tetrahalide UX(4) (X = Cl, Br, I)/Ethyl Acetate System

[Image: see text] The reaction of the uranium(IV) halides UCl(4), UBr(4), or UI(4) with ethyl acetate (EtOAc) leads to the formation of the complexes [UX(3)(EtOAc)(4)][UX(5)(EtOAc)] (X = Cl, Br) or [UI(4)(EtOAc)(3)]. Thus, both UCl(4) and UBr(4) show self-ionization in ethyl acetate to a distorted p...

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Detalles Bibliográficos
Autores principales: Deubner, H. Lars, Graubner, Tim, Buchner, Magnus R., Weigend, Florian, Ivlev, Sergei I., Karttunen, Antti J., Kraus, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9016826/
https://www.ncbi.nlm.nih.gov/pubmed/35449913
http://dx.doi.org/10.1021/acsomega.2c00175

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9016826/
https://www.ncbi.nlm.nih.gov/pubmed/35449913
http://dx.doi.org/10.1021/acsomega.2c00175

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