Toward asymmetric aziridination with an iron complex supported by a D(2)-symmetric tetra-NHC

A neutral D(2)-symmetric macrocyclic tetra-N-heterocyclic carbene ligand was synthesized. The macrocycle was ligated to iron(ii) via transmetalation from an isolated silver complex that has two conformers. The iron complex catalyzed the first stereospecific aziridination between aryl azides and alip...

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Detalles Bibliográficos
Autores principales: Blatchford, Kevin M., Mize, Carson J., Roy, Sharani, Jenkins, David M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9019631/
https://www.ncbi.nlm.nih.gov/pubmed/35380151
http://dx.doi.org/10.1039/d2dt00772j
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author Blatchford, Kevin M.
Mize, Carson J.
Roy, Sharani
Jenkins, David M.
author_facet Blatchford, Kevin M.
Mize, Carson J.
Roy, Sharani
Jenkins, David M.
author_sort Blatchford, Kevin M.
collection PubMed
description A neutral D(2)-symmetric macrocyclic tetra-N-heterocyclic carbene ligand was synthesized. The macrocycle was ligated to iron(ii) via transmetalation from an isolated silver complex that has two conformers. The iron complex catalyzed the first stereospecific aziridination between aryl azides and aliphatic alkenes, albeit with low ee's.
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spelling pubmed-90196312022-06-01 Toward asymmetric aziridination with an iron complex supported by a D(2)-symmetric tetra-NHC Blatchford, Kevin M. Mize, Carson J. Roy, Sharani Jenkins, David M. Dalton Trans Chemistry A neutral D(2)-symmetric macrocyclic tetra-N-heterocyclic carbene ligand was synthesized. The macrocycle was ligated to iron(ii) via transmetalation from an isolated silver complex that has two conformers. The iron complex catalyzed the first stereospecific aziridination between aryl azides and aliphatic alkenes, albeit with low ee's. The Royal Society of Chemistry 2022-04-05 /pmc/articles/PMC9019631/ /pubmed/35380151 http://dx.doi.org/10.1039/d2dt00772j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Blatchford, Kevin M.
Mize, Carson J.
Roy, Sharani
Jenkins, David M.
Toward asymmetric aziridination with an iron complex supported by a D(2)-symmetric tetra-NHC
title Toward asymmetric aziridination with an iron complex supported by a D(2)-symmetric tetra-NHC
title_full Toward asymmetric aziridination with an iron complex supported by a D(2)-symmetric tetra-NHC
title_fullStr Toward asymmetric aziridination with an iron complex supported by a D(2)-symmetric tetra-NHC
title_full_unstemmed Toward asymmetric aziridination with an iron complex supported by a D(2)-symmetric tetra-NHC
title_short Toward asymmetric aziridination with an iron complex supported by a D(2)-symmetric tetra-NHC
title_sort toward asymmetric aziridination with an iron complex supported by a d(2)-symmetric tetra-nhc
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9019631/
https://www.ncbi.nlm.nih.gov/pubmed/35380151
http://dx.doi.org/10.1039/d2dt00772j
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