Self-Assembly of Au–Ag Alloy Hollow Nanochains for Enhanced Plasmon-Driven Surface-Enhanced Raman Scattering

In this paper, Au–Ag alloy hollow nanochains (HNCs) were successfully prepared by a template-free self-assembly method achieved by partial substitution of ligands. The obtained Au–Ag alloy HNCs exhibit stronger enhancement as surface-enhanced Raman scattering (SERS) substrates than Au–Ag alloy hollo...

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Detalles Bibliográficos
Autores principales: Liu, Weiyan, Zhang, Jianwen, Hou, Juan, Aziguli, Haibibu, Zhang, Qiming, Jiang, Hu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9025440/
https://www.ncbi.nlm.nih.gov/pubmed/35457952
http://dx.doi.org/10.3390/nano12081244
Descripción
Sumario:In this paper, Au–Ag alloy hollow nanochains (HNCs) were successfully prepared by a template-free self-assembly method achieved by partial substitution of ligands. The obtained Au–Ag alloy HNCs exhibit stronger enhancement as surface-enhanced Raman scattering (SERS) substrates than Au–Ag alloy hollow nanoparticles (HNPs) and Au nanochains substrates with an intensity ratio of about 1.3:1:1. Finite difference time domain (FDTD) simulations show that the SERS enhancement of Au–Ag alloy HNCs substrates is produced by a synergistic effect between the plasmon hybridization effect associated with the unique alloy hollow structure and the strong “hot spot” in the interstitial regions of the nanochains.

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