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Over 65% Sunlight Absorption in a 1 μm Si Slab with Hyperuniform Texture

[Image: see text] Thin, flexible, and invisible solar cells will be a ubiquitous technology in the near future. Ultrathin crystalline silicon (c-Si) cells capitalize on the success of bulk silicon cells while being lightweight and mechanically flexible, but suffer from poor absorption and efficiency...

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Detalles Bibliográficos
Autores principales: Tavakoli, Nasim, Spalding, Richard, Lambertz, Alexander, Koppejan, Pepijn, Gkantzounis, Georgios, Wan, Chenglong, Röhrich, Ruslan, Kontoleta, Evgenia, Koenderink, A. Femius, Sapienza, Riccardo, Florescu, Marian, Alarcon-Llado, Esther
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9026274/
https://www.ncbi.nlm.nih.gov/pubmed/35480493
http://dx.doi.org/10.1021/acsphotonics.1c01668
Descripción
Sumario:[Image: see text] Thin, flexible, and invisible solar cells will be a ubiquitous technology in the near future. Ultrathin crystalline silicon (c-Si) cells capitalize on the success of bulk silicon cells while being lightweight and mechanically flexible, but suffer from poor absorption and efficiency. Here we present a new family of surface texturing, based on correlated disordered hyperuniform patterns, capable of efficiently coupling the incident spectrum into the silicon slab optical modes. We experimentally demonstrate 66.5% solar light absorption in free-standing 1 μm c-Si layers by hyperuniform nanostructuring for the spectral range of 400 to 1050 nm. The absorption equivalent photocurrent derived from our measurements is 26.3 mA/cm(2), which is far above the highest found in literature for Si of similar thickness. Considering state-of-the-art Si PV technologies, we estimate that the enhanced light trapping can result in a cell efficiency above 15%. The light absorption can potentially be increased up to 33.8 mA/cm(2) by incorporating a back-reflector and improved antireflection, for which we estimate a photovoltaic efficiency above 21% for 1 μm thick Si cells.