Supramolecular Hydrogen Bonding Assembly from Non-Coplanar Aromatic Tetra-(1)H-Pyrazoles with Crystallization-Induced Emission (CIE)

Here, we report a design strategy for constructing supramolecular organic frameworks by introducing (1)H-pyrazole groups to aromatic cores as non-coplanar molecules to form diverse supramolecular assemblies through multiple (1)H-pyrazole [N−H···N] hydrogen bonds as well as other weak interactions. T...

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Detalles Bibliográficos
Autores principales: Wang, Ji, Zhao, Li-Rong, Tong, Jin, Yu, Yan-Min, Wang, Xia-Yan, Yu, Shu-Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9026852/
https://www.ncbi.nlm.nih.gov/pubmed/35457024
http://dx.doi.org/10.3390/ijms23084206
Descripción
Sumario:Here, we report a design strategy for constructing supramolecular organic frameworks by introducing (1)H-pyrazole groups to aromatic cores as non-coplanar molecules to form diverse supramolecular assemblies through multiple (1)H-pyrazole [N−H···N] hydrogen bonds as well as other weak interactions. The new supramolecular organic frameworks displayed interesting crystallization-induced emission (CIE) behavior.

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