Polypropylene Hollow-Fiber Membrane Made Using the Dissolution-Induced Pores Method

The efficient preparation of hydrophilic polypropylene membranes has always been a problem. Here, a twin-screw extruder was used to melt-blend ethylene-vinyl alcohol copolymer and polypropylene; then, hollow fibers were extrusion-molded with a spinneret and taken by a winder; after this, dimethyl sulfoxide was used to dissolve the ethylene-vinyl alcohol copolymer of the fiber to obtain a polypropylene hollow-fiber membrane. This procedure was used to study the effects of different contents and segment structure of ethylene-vinyl alcohol copolymer on the structure and filtration performance of the membranes; furthermore, the embedded factor and blocked factor were used to evaluate the ethylene-vinyl alcohol copolymer embedded in the matrix without dissolving and or being completely blocked in the matrix, respectively. The results show that the increase in ethylene-vinyl alcohol copolymer could reduce the embedded factor and increase the blocked factor. The increase in the polyethylene segments of ethylene-vinyl alcohol copolymer could increase both the embedded factor and blocked factor. The water permeation of the membrane reached 1300 Lm(−2)·h(−1)·bar(−1) with a 100% rejection of ink (141 nm) and the elongation at break reached 188%, while the strength reached 22 MPa. The dissolution-induced pores method provides a completely viable alternative route for the preparation of polypropylene membranes.