Cargando…

Insights on Shear Transfer Efficiency in “Brick-and-Mortar” Composites Made of 2D Carbon Nanoparticles

Achieving high mechanical performances in nanocomposites reinforced with lamellar fillers has been a great challenge in the last decade. Many efforts have been made to fabricate synthetic materials whose properties resemble those of the reinforcement. To achieve this, special architectures have been...

Descripción completa

Detalles Bibliográficos
Autores principales: Cilento, Fabrizia, Martone, Alfonso, Giordano, Michele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9027589/
https://www.ncbi.nlm.nih.gov/pubmed/35458067
http://dx.doi.org/10.3390/nano12081359
Descripción
Sumario:Achieving high mechanical performances in nanocomposites reinforced with lamellar fillers has been a great challenge in the last decade. Many efforts have been made to fabricate synthetic materials whose properties resemble those of the reinforcement. To achieve this, special architectures have been considered mimicking existing materials, such as nacre. However, achieving the desired performances is challenging since the mechanical response of the material is influenced by many factors, such as the filler content, the matrix molecular mobility and the compatibility between the two phases. Most importantly, the properties of a macroscopic bulk material strongly depend on the interaction at atomic levels and on their synergetic effect. In particular, the formation of highly-ordered brick-and-mortar structures depends on the interaction forces between the two phases. Consequently, poor mechanical performances of the material are associated with interface issues and low stress transfer from the matrix to the nanoparticles. Therefore, improvement of the interface at the chemical level enhances the mechanical response of the material. The purpose of this review is to give insight into the stress transfer mechanism in high filler content composites reinforced with 2D carbon nanoparticles and to describe the parameters that influence the efficiency of stress transfer and the strategies to improve it.