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The Al(61.49)Mn(11.35)Ni(4) phase in the Al–Mn–Ni system
An intermetallic phase in the Al–Mn–Ni system crystallizing in space group Cmcm (No. 63) and refined formula Al(61.49)Mn(11.35)Ni(4) (called the R′ phase) has been synthesized by high-temperature sintering of a mixture with initial chemical composition Al(60)Mn(7)Ni(3). In comparison with the stru...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028548/ https://www.ncbi.nlm.nih.gov/pubmed/36337092 http://dx.doi.org/10.1107/S2414314622000384 |
Sumario: | An intermetallic phase in the Al–Mn–Ni system crystallizing in space group Cmcm (No. 63) and refined formula Al(61.49)Mn(11.35)Ni(4) (called the R′ phase) has been synthesized by high-temperature sintering of a mixture with initial chemical composition Al(60)Mn(7)Ni(3). In comparison with the structure model of the previously reported R phase with composition Al(60)Mn(11)Ni(4) [Robinson (1954 ▸). Acta Cryst. 7, 494–497], there are two mutually exchanged Mn and Ni sites together with one positionally disordered Al site [occupancy ratio 0.811 (8):0.121 (7)] and one partially occupied Mn site [s.o.f. 0.677 (5)] in the current structure model of the R′ phase. [Image: see text] |
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