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N-Phenyl-N-[(E)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethenyl]aniline
The title compound, C(20)H(24)BNO(2), has a polarized π-system due to significant resonance between the N—C(H)=C(H)—B and ionic N(+)=C(H)—C(H)=B(−) canonical forms. The dihedral angles between the NC(2)B plane (r.m.s. deviation 0.0223 Å) and the C(3)N (r.m.s. deviation 0.0025 Å) and BCO(2) (r.m.s. d...
Autores principales: | Hatayama, Yuki, Akagi, Kazuto, Okuno, Tsunehisa |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028550/ https://www.ncbi.nlm.nih.gov/pubmed/36337091 http://dx.doi.org/10.1107/S2414314622000839 |
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