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Bis­(di­methylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II)

In the title compound, [Cu(C(9)H(6)N(3)O(2))(2)(C(2)H(7)N)(2)], the Cu(2+) cation is situated on an inversion center and is coordinated by the N atoms of two di­methyl­amine ligands and the carboxyl­ate O atoms of two 4-(1,2,4-triazol-1-yl)benzoate anions, leading to a slightly distorted square-plan...

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Detalles Bibliográficos
Autores principales: Liu, Lin, Han, Zheng-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028552/
https://www.ncbi.nlm.nih.gov/pubmed/36337093
http://dx.doi.org/10.1107/S2414314622000463
Descripción
Sumario:In the title compound, [Cu(C(9)H(6)N(3)O(2))(2)(C(2)H(7)N)(2)], the Cu(2+) cation is situated on an inversion center and is coordinated by the N atoms of two di­methyl­amine ligands and the carboxyl­ate O atoms of two 4-(1,2,4-triazol-1-yl)benzoate anions, leading to a slightly distorted square-planar N(2)O(2) coordination environment. In the crystal, inter­molecular N—H⋯N hydrogen bonds between the amine function and the central N atom of the triazole ring lead to the formation of ribbons parallel to [1 [Image: see text] 1]. Weak inter­molecular C—H⋯O hydrogen-bonding inter­actions are also observed that consolidate the crystal packing. [Image: see text]