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Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II)
In the title compound, [Cu(C(9)H(6)N(3)O(2))(2)(C(2)H(7)N)(2)], the Cu(2+) cation is situated on an inversion center and is coordinated by the N atoms of two dimethylamine ligands and the carboxylate O atoms of two 4-(1,2,4-triazol-1-yl)benzoate anions, leading to a slightly distorted square-plan...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028552/ https://www.ncbi.nlm.nih.gov/pubmed/36337093 http://dx.doi.org/10.1107/S2414314622000463 |
Sumario: | In the title compound, [Cu(C(9)H(6)N(3)O(2))(2)(C(2)H(7)N)(2)], the Cu(2+) cation is situated on an inversion center and is coordinated by the N atoms of two dimethylamine ligands and the carboxylate O atoms of two 4-(1,2,4-triazol-1-yl)benzoate anions, leading to a slightly distorted square-planar N(2)O(2) coordination environment. In the crystal, intermolecular N—H⋯N hydrogen bonds between the amine function and the central N atom of the triazole ring lead to the formation of ribbons parallel to [1 [Image: see text] 1]. Weak intermolecular C—H⋯O hydrogen-bonding interactions are also observed that consolidate the crystal packing. [Image: see text] |
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