Cargando…
Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II)
In the title compound, [Cu(C(9)H(6)N(3)O(2))(2)(C(2)H(7)N)(2)], the Cu(2+) cation is situated on an inversion center and is coordinated by the N atoms of two dimethylamine ligands and the carboxylate O atoms of two 4-(1,2,4-triazol-1-yl)benzoate anions, leading to a slightly distorted square-plan...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028552/ https://www.ncbi.nlm.nih.gov/pubmed/36337093 http://dx.doi.org/10.1107/S2414314622000463 |
_version_ | 1784691647920996352 |
---|---|
author | Liu, Lin Han, Zheng-Bo |
author_facet | Liu, Lin Han, Zheng-Bo |
author_sort | Liu, Lin |
collection | PubMed |
description | In the title compound, [Cu(C(9)H(6)N(3)O(2))(2)(C(2)H(7)N)(2)], the Cu(2+) cation is situated on an inversion center and is coordinated by the N atoms of two dimethylamine ligands and the carboxylate O atoms of two 4-(1,2,4-triazol-1-yl)benzoate anions, leading to a slightly distorted square-planar N(2)O(2) coordination environment. In the crystal, intermolecular N—H⋯N hydrogen bonds between the amine function and the central N atom of the triazole ring lead to the formation of ribbons parallel to [1 [Image: see text] 1]. Weak intermolecular C—H⋯O hydrogen-bonding interactions are also observed that consolidate the crystal packing. [Image: see text] |
format | Online Article Text |
id | pubmed-9028552 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-90285522022-11-04 Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II) Liu, Lin Han, Zheng-Bo IUCrdata Data Reports In the title compound, [Cu(C(9)H(6)N(3)O(2))(2)(C(2)H(7)N)(2)], the Cu(2+) cation is situated on an inversion center and is coordinated by the N atoms of two dimethylamine ligands and the carboxylate O atoms of two 4-(1,2,4-triazol-1-yl)benzoate anions, leading to a slightly distorted square-planar N(2)O(2) coordination environment. In the crystal, intermolecular N—H⋯N hydrogen bonds between the amine function and the central N atom of the triazole ring lead to the formation of ribbons parallel to [1 [Image: see text] 1]. Weak intermolecular C—H⋯O hydrogen-bonding interactions are also observed that consolidate the crystal packing. [Image: see text] International Union of Crystallography 2022-01-14 /pmc/articles/PMC9028552/ /pubmed/36337093 http://dx.doi.org/10.1107/S2414314622000463 Text en © Liu and Han 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Liu, Lin Han, Zheng-Bo Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II) |
title | Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II) |
title_full | Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II) |
title_fullStr | Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II) |
title_full_unstemmed | Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II) |
title_short | Bis(dimethylamine-κN)bis[4-(1,2,4-triazol-1-yl)benzoato-κO]copper(II) |
title_sort | bis(dimethylamine-κn)bis[4-(1,2,4-triazol-1-yl)benzoato-κo]copper(ii) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9028552/ https://www.ncbi.nlm.nih.gov/pubmed/36337093 http://dx.doi.org/10.1107/S2414314622000463 |
work_keys_str_mv | AT liulin bisdimethylamineknbis4124triazol1ylbenzoatokocopperii AT hanzhengbo bisdimethylamineknbis4124triazol1ylbenzoatokocopperii |