Mechanical, Leaching, and Microstructure Properties of Mine Waste Rock Reinforced and Stabilised with Waste Oyster Shell for Road Subgrade Use

Two waste materials, oyster shell (NCOS; non-calcined oyster shell as coarse aggregate and COSP; calcined oyster shell powder as total and partial cement replacement) are used to reinforce and stabilise poorly graded and heavy metal-contaminated mine waste rock (MWR) for pavement subgrade use. Mechanical, leaching, and microstructural tests and analysis were performed on reinforced and stabilised samples to evaluate the effectiveness of the reinforcement and stabilisation of the MWR. Experimental results revealed NCOS and COSP improved the mechanical, leaching, and microstructural properties of the stabilised composite, with a 5% cement–15% COSP–15% NCOS mix being optimal when compared to the control mixes of cement only and no- NCOS. Higher COSP contents beyond 10% reduced the heavy metal contents significantly, but with relatively lower unconfined compressive strengths. Microstructural test results revealed the formation of calcium silicate hydrate (CSH), calcium aluminium silicate hydrate (CASH), ettringite, and calcite as the stabilisation products. Heavy metal complexes in both the cement-only and cement–NCOS–COSP mixes were also found. It is concluded that NCOS reinforced and improved the grading of poorly graded MWR, and that COSP stabilised and immobilised heavy metals present in MWR, thereby improving strength and other engineering properties for subgrade use.