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Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance
A new strategy to synthesise carbon/TiO(2) gel by a sol–gel method is proposed. Textural, morphological, and chemical properties were characterised in detail and the synthesised material was proven to be an active adsorbent, as well as a visible light photocatalyst. Homogenously distributed TiO(2) i...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9031654/ https://www.ncbi.nlm.nih.gov/pubmed/35448117 http://dx.doi.org/10.3390/gels8040215 |
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author | Safri, Anam Fletcher, Ashleigh Jane |
author_facet | Safri, Anam Fletcher, Ashleigh Jane |
author_sort | Safri, Anam |
collection | PubMed |
description | A new strategy to synthesise carbon/TiO(2) gel by a sol–gel method is proposed. Textural, morphological, and chemical properties were characterised in detail and the synthesised material was proven to be an active adsorbent, as well as a visible light photocatalyst. Homogenously distributed TiO(2) is mesoporous with high surface area and, hence, exhibited a high adsorption capacity. The adsorption equilibrium experimental data were well explained by the Sips isotherm model. Kinetic experiments demonstrated that experimental data fitted a pseudo second order model. The modification in electronic structure of TiO(2) resulted in a reduced bandgap compared to commercial P25. The absorption edge studied through UV-Vis shifted to the visible region, hence, daylight photocatalytic activity was efficient against degradation of MB dye, as an example pollutant molecule. The material was easily removed post treatment, demonstrating potential for employment in industrial water treatment processes. |
format | Online Article Text |
id | pubmed-9031654 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-90316542022-04-23 Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance Safri, Anam Fletcher, Ashleigh Jane Gels Article A new strategy to synthesise carbon/TiO(2) gel by a sol–gel method is proposed. Textural, morphological, and chemical properties were characterised in detail and the synthesised material was proven to be an active adsorbent, as well as a visible light photocatalyst. Homogenously distributed TiO(2) is mesoporous with high surface area and, hence, exhibited a high adsorption capacity. The adsorption equilibrium experimental data were well explained by the Sips isotherm model. Kinetic experiments demonstrated that experimental data fitted a pseudo second order model. The modification in electronic structure of TiO(2) resulted in a reduced bandgap compared to commercial P25. The absorption edge studied through UV-Vis shifted to the visible region, hence, daylight photocatalytic activity was efficient against degradation of MB dye, as an example pollutant molecule. The material was easily removed post treatment, demonstrating potential for employment in industrial water treatment processes. MDPI 2022-04-01 /pmc/articles/PMC9031654/ /pubmed/35448117 http://dx.doi.org/10.3390/gels8040215 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Safri, Anam Fletcher, Ashleigh Jane Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance |
title | Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance |
title_full | Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance |
title_fullStr | Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance |
title_full_unstemmed | Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance |
title_short | Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance |
title_sort | effective carbon/tio(2) gel for enhanced adsorption and demonstrable visible light driven photocatalytic performance |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9031654/ https://www.ncbi.nlm.nih.gov/pubmed/35448117 http://dx.doi.org/10.3390/gels8040215 |
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